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The unit which was formed from

机译:由以下单位组成的单位

摘要

PROBLEM TO BE SOLVED: To obtain a target resin by improving the reaction conversion of a sublimable diol in conducting the polycondensation step in producing a copolyester resin using the sublimable diol as the raw material and to provide a method for stably producing the resin without clogging the reduced-pressure portions of piping and the like in the production apparatus due to the sublimation of the sublimable diol.;SOLUTION: The method produces a copolyester resin comprising a dicarboxylic acid constituting unit and a diol constituting unit and, simultaneously, a unit formed from a sublimable diol in the diol constituting unit by (1) a step of distilling off water and/or an alcohol to produce an oligomer, (2) a step of mainly distilling off a nonsublimable diol to perform transesterification until the amount of the sublimable diol comes to ≤10 wt.% based on its added amount, and (3) a step of allowing the oligomer to have a high molecular weight under reduced pressure.;COPYRIGHT: (C)2003,JPO
机译:要解决的问题:通过在使用可升华二醇作为原料生产共聚酯树脂的缩聚步骤中进行可缩聚步骤中的可升华二醇的反应转化率得到改善,从而获得目标树脂,并提供一种稳定地生产树脂而不会堵塞树脂的方法。由于可升华二醇的升华,生产设备中的管道等的减压部分。解决方案:该方法生产的共聚酯树脂包括二羧酸构成单元和二醇构成单元,同时还包括由二醇构成单元中的可升华二醇,其通过以下步骤:(1)蒸馏出水和/或醇以制备低聚物的步骤,(2)主要蒸馏出不可升华的二醇以进行酯交换反应直到可升华的二醇的量的步骤以其添加量为基准计,其含量为& 10wt。%,并且(3)在减压下使低聚物具有高分子量的步骤。电话:(C)2003,日本特许厅

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