Production method and optical active spiral polymer polymerization initiator of optical active spiral polymer

摘要

Low and the optical active narasen polymer where also the time when it is necessary for the polymerization at room temperature is quick is offered at price optical activity by doing the asymmetry polymerization which uses the organic nickel complex as the asymmetrical polymerization catalyst. Being production method of the optical active spiral polymer which possesses the process which concretely, (A) the aromatic compound or aromatic complex ring chemical compound and (B) mixes with the jiisonitoriru chemical compound which possesses the respective isonitoriru basis in two unsaturated carbons which (D) it adjoins with process, and the aforementioned reactant which (C) react the nickel compound under existing of the ligand makes jiisonitoriru chemical compound polymerize, the aforementioned aromatic compound or aromatic complex ring chemical compound (A) and the aforementioned ligand (C) at least in each case it is production method of the optical active spiral polymer which features that one side it is optical activity.