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The vanadate of the rare earth element or colloid dispersing element null of the phospho vanadate

机译:稀土元素的钒酸盐或胶体分散元素的钒酸盐无效

摘要

In the colloidal dispersion of particles of the phosphodiester vanadate or vanadium salt of one rare-earth element, the present invention is formed by the rare earth elements (complexing agent pK of 2.5 or more as a complexing agent at least on colloidal dispersion characterized in that it comprises one of the anions of the monovalent acid having a pKa of 2.5 to 5 soluble in water or which have an extra logarithm) of the dissociation constant of the complex is. In the case of vanadate dispersion, the particles have an average size of at most 6nm. The dispersion of the present invention, the pH is adjusted to a value of at least 7 and an initial colloidal dispersion of rare earth element at least one compound containing an anion of an acid or a monovalent complexing agent at least one An initial dispersion of complexes based on anions of monovalent acid rare earth element compound, or a complexing agent or things,, OH - and further contain anions, the pH is adjusted to a value of at least 7 is obtained by heating the said medium, and adjusted to a value of at least 9 and the pH of the medium in which phosphate ions both into contact if necessary were but also, and vanadate ions one, was obtained.
机译:在一种稀土元素的钒的磷酸二酯钒酸盐或钒盐的颗粒的胶态分散体中,本发明由稀土元素(至少作为络合剂的络合剂pK为2.5以上)形成,其特征在于,它包含pKa为2.5至5的一价酸阴离子之一,该阴离子可溶于水或具有对数的复合物解离常数。在钒酸盐分散体的情况下,颗粒的平均尺寸至多为6nm。将本发明的分散体的pH调节至至少7,并且稀土元素的初始胶体分散体至少一种包含酸的阴离子或单价络合剂的化合物至少一种。基于一价酸稀土元素化合物或络合剂或阴离子OH -的阴离子并进一步含有阴离子,通过加热所述pH值至至少7调节至至少9的pH值,并获得其中必要时可彼此接触的磷酸根离子和钒酸盐离子之一的pH值。

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