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Method for Producing Deuterium Gas and Catalytic Deuteration Method Using Deuterium Gas Obtained Thereby

机译:氘气的制造方法及由此获得的氘气的催化氘化方法

摘要

[PROBLEMS] To provide a method for producing heavy hydrogen gas, which enables heavy hydrogen gas to be efficiently produced from a deuterated solvent as a reaction substrate.;[MEANS FOR SOLVING PROBLEMS] (1) A method for producing heavy hydrogen gas, comprising bringing a deuterated solvent into contact with hydrogen gas under pressure in the coexistence with a catalyst selected from a palladium catalyst, a platinum catalyst, a nickel catalyst, a cobalt catalyst, an iridium catalyst, and a rhodium catalyst and a ruthenium catalyst which are not coordinated with a ligand, and (2) a catalytic deuteration method of a compound having a reducible functional group, comprising bringing the heavy hydrogen gas obtained by the above (1) into contact with the compound having a reducible functional group in the coexistence with a catalytic reduction catalyst.
机译:[问题]提供一种重氢气的生产方法,其使得能够从氘代溶剂作为反应底物有效地生产重氢气。[解决问题的方法](1)一种重氢气的生产方法,包括使氘化溶剂在压力下与选自以下的钯催化剂,铂催化剂,镍催化剂,钴催化剂,铱催化剂,铑催化剂和钌催化剂并存的氢气与氢气接触。 (2)具有可还原官能团的化合物的催化氘代方法,其包括使通过上述(1)获得的重氢与具有可还原官能团的化合物在与氢共存的条件下接触。催化还原催化剂。

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