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Method For Decarboxylating C-C Cross-Linking Of Carboxylic Acids With Carbon Electrophiles

机译:碳亲电体使羧酸C-C交联脱羧的方法

摘要

The invention relates to a method for decarboxylating C—C bond formation by reacting carboxylic salts with carbon electrophiles in the presence of transition metal compounds as catalysts. The method represents a decarboxylating C—C bond formation of carboxylic acid salts with carbon electrophiles, wherein the catalyst contains two transition metals and/or transition metal compounds, from which one is present, preferably, in the oxidation step, which are different from each other by one unit, and catalyzes a radical decarboxylation which is absorbed during the second oxidation steps, which are different from each other by two units and catalyzes the two electron processes of a C—C bond formation reaction.
机译:本发明涉及通过在过渡金属化合物作为催化剂的存在下使羧酸盐与碳亲电试剂反应而使CC键形成脱羧的方法。该方法代表了羧酸盐与碳亲电试剂的脱羧CC键形成,其中催化剂包含两种过渡金属和/或过渡金属化合物,优选在氧化步骤中存在两种过渡金属和/或过渡金属化合物,每种均不同彼此催化一个单元,并且催化在第二氧化步骤中被吸收的自由基脱羧,所述自由基脱羧彼此之间相差两个单元,并且催化CC键形成反应的两个电子过程。

著录项

  • 公开/公告号US2008177114A1

    专利类型

  • 公开/公告日2008-07-24

    原文格式PDF

  • 申请/专利权人 LUKAS GOOSSEN;GUOJUN DENG;

    申请/专利号US20060913626

  • 发明设计人 LUKAS GOOSSEN;GUOJUN DENG;

    申请日2006-05-10

  • 分类号C07C205/06;B01J23/72;B01J31/02;

  • 国家 US

  • 入库时间 2022-08-21 20:14:39

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