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CATALYST PREPARED BY IMPREGNATION OF AN AQUEOUS SOLUTION CONTAINING OXY(HYDROXIDE) PARTICLES OF A CATION IN INTERACTION WITH A MOLECULAR SPECIES OF A GROUP VIII METAL
CATALYST PREPARED BY IMPREGNATION OF AN AQUEOUS SOLUTION CONTAINING OXY(HYDROXIDE) PARTICLES OF A CATION IN INTERACTION WITH A MOLECULAR SPECIES OF A GROUP VIII METAL
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机译:通过浸渍与第八族金属分子相互作用的阳离子的氢氧根氧化物水溶液制备的催化剂
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摘要
The invention concerns a process for preparing a catalyst precursor comprising the following steps:1)a) preparing a colloidal solution A with a defined pH containing oxy(hydroxide) particles of a cation Mz+ selected from the group constituted by cations from columns IIA, IIIA, IIIB, IVB and IVA of the periodic table; or1)b) using a commercial aqueous colloidal solution (solution A) with a defined pH containing oxy(hydroxide) particles of a cation Mz+ selected from the group constituted by cations from columns IIA, IIIA, IIIB, IVB and IVA of the periodic table;2) adding in an aqueous solution B containing a precursor salt of a group VIII metal with a concentration of 0.001 to 1 mole/litre, the precursor salt of the metal being soluble under the pH conditions used in step 1.;The invention also concerns the catalyst obtained from a catalyst precursor and its application in selective hydrogenation.
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机译:本发明涉及一种制备催化剂前体的方法,包括以下步骤: 1)a)制备胶体溶液A,该胶体溶液A的定义pH值包含阳离子的氧(羟基)粒子从元素周期表的IIA,IIIA,IIIB,IVB和IVA列的阳离子组成的组中选择的M z + Sup>;或 ListItem> 1)b),使用具有规定pH值的包含阳离子M z + Sup>选自周期表中IIA,IIIA,IIIB,IVB和IVA列的阳离子组成的组; ListItem> 2)在水溶液B中加入浓度为0.001至1摩尔/升的VIII族金属的前体盐,该金属的前体盐在步骤1所用的pH条件下可溶。 ListItem> UnorderedList本发明还涉及由催化剂前体获得的催化剂及其在选择性加氢中的应用。
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