Method For The Preparation Of X-Ray Amorphous Or Weakly Crystalline Metal Oxide Fluorides And New Uses Thereof

摘要

The present invention is related to a method for preparing an X-ray amorphous or weakly crystalline metal oxide fluoride of a composition represented by the formula M^a+O_bF_c comprising the steps of b) providing a precursor, whereby the precursor is a fluorinated metal compound having a composition which is represented by the formula M^a+F_(a−d)B_dL_xb) converting the precursor into an metal oxide/hydroxide fluoride; and c) calcinating the metal oxide/hydroxide fluoride having the formula M^a+O_cH_fF_c to generate the X-ray amorphous or weakly crystalline metal oxide fluoride of the formula M^a+O_bF_c, whereby M is selected from the group comprising metals of the first, second, third and fourth main group and any subgroup of the periodic table; B is a group or an anion which is selected from the group comprising alkoxide, enolates, alkyl, chloride, bromide, iodide, nitrate, and organic acid anions; B is preferably an alkoxy group; L is a solvent other than water; a is any integer of 1, 2, 3, 4, 5 or 6, preferably 2 or 3; and b and c are any numbers obeying the formula b/2+c=a, and c is 0.1b to 10b; d is a number between 0 and 0.8a, preferable between 0.1 and 0.3a; e is (a−c+f)/2; f is a number between 0 and (a−c); and x is between 0 and 6.