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Ethylene-Based Polymer Microparticles, Functional Group-Containing Ethylene-Based Polymer Microparticles,and Catalyst Carriers for Manufacture Thereof

机译:乙烯类聚合物微粒,含官能团的乙烯类聚合物微粒及其制造用催化剂载体

摘要

Ethylene-based copolymer microparticles and functional group-containing ethylene-based copolymer microparticles that have particle diameter smaller than that of conventional polyethylene fine-particles, no inter-particle agglomeration, very narrow particle size distribution, and high sphericity are provided, in which requirements (A) to (E): (A) The intrinsic viscosity [η] measured in decalin at 135° C. is in the range of 0.1 to 50 dl/g, (B) at least 95 wt % or more of particles pass through a mesh screen with an opening of 37 μm, (C) the median diameter (d50) measured by laser diffraction scattering is 3 μm≦d50≦25 μm, (D) the circularity coefficient is 0.85 or more, and (E) the variation coefficient of particle diameter (Cv) is 20% or less. Non-agglomerated spherical magnesium-containing microparticles used as magnesium-containing carrier component for olefin-polymerization catalysts that can manufacture the above microparticles are also provided.
机译:提供了粒径比常规聚乙烯微粒的粒径小,没有粒子间的团聚,非常窄的粒径分布和高球形度的乙烯类共聚物微粒和含官能团的乙烯类共聚物微粒。 (A)至(E):(A)在萘烷中在135℃下测量的特性粘度[η]在0.1至50dl / g的范围内,(B)至少95wt%或更多的颗粒通过通过具有37μm开口的网筛,(C)通过激光衍射散射测量的中值直径(d 50 )为3μm≤d 50 ≤25μm, (D)圆度系数为0.85以上,(E)粒径(Cv)的变化系数为20%以下。还提供了非凝集的球形的含镁的微粒,其用作可以制造上述微粒的烯烃聚合催化剂的含镁的载体组分。

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