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Process for reducing the sulfur content of a petroleum fraction, fluidizable catalyst additive for reducing sulfur content, and integrated fluidizable catalyst for sulfur reduction in catalytic cracking product

机译:降低石油馏分中硫含量的方法,用于降低硫含量的可流化催化剂添加剂和用于催化裂化产物中硫还原的整体可流化催化剂

摘要

The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction additive comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve. The molecular sieve is normally a large pore size zeolite such as USY or zeolite beta or an intermediate pore size zeolite such as ZSM-5. The metal is normally a metal of Period 3 of the Periodic Table, preferably zinc or vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.
机译:催化裂化过程中液体裂化产品(特别是裂化汽油)的硫含量可通过使用硫还原添加剂来降低,该添加剂包括多孔分子筛,该分子筛在孔结构内部包含一种氧化态的金属,该金属的氧化态大于零。筛子。分子筛通常是大孔径的沸石,例如USY或β沸石,或中等孔径的沸石,例如ZSM-5。该金属通常是元素周期表的周期3的金属,优选锌或钒。硫还原催化剂可以以单独的颗粒添加剂的形式使用或作为整体裂化/硫还原催化剂的组分使用。

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