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Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals
Process for transition metal free catalytic aerobic oxidation of alcohols under mild conditions using stable free nitroxyl radicals
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机译:在温和条件下使用稳定的游离硝基氧基自由基进行醇的无过渡金属催化有氧氧化的方法
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摘要
An alcohol can be oxidized by a process in which a primary or secondary alcohol are reacted with an oxygen-containing gas in the presence of a catalyst composition containing (i) a stable free nitroxyl radical derivative, (ii) a nitrate source, (iii) a bromide source, and (iiii) a carboxylic acid, thereby obtaining an aldehyde or a ketone.
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