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METHOD AND APPARATUS FOR RECOVERING INDIUM FROM WASTE LIQUID CRYSTAL DISPLAY

机译:从废液结晶显示中回收铟的方法和装置

摘要

This invention provides a method and apparatus for recovering In in the form of an alloy or a metal simple substance as a valuable material from waste LCD. In the In recovery method and apparatus, there is no need to recover In as indium hydroxide, and In can be recovered as a valuable metal. Accordingly, unlike the case of indium hydroxide, the recovery does not suffer from poor handling, and In can easily be recovered through a filter or the like with significantly improved In recovery. The In recovery method is characterized by comprising crushing waste LCD containing indium tin oxide, dissolving indium tin oxide from the crushed waste LCD with an acid to give an indium compound-containing solution, allowing the solution to flow into a reactor for recovery and, further, adding particles of a metal having a larger ionization tendency than In into the reactor for recovery, fluidizing the metal particles, precipitating In or an In alloy contained in the indium compound-containing solution onto the surface of the metal particles, then separating the precipitated In or In alloy from the metal particles by separation means, and separating and recovering the separated solid In or In alloy from the liquid component.
机译:本发明提供了一种从废LCD中回收作为有价值的材料的合金或金属单质形式的In的方法和设备。在In回收方法和装置中,不需要以氢氧化铟的形式回收In,并且可以将In回收为有价值的金属。因此,与氢氧化铟的情况不同,回收率不会受到不良处理的影响,并且可以通过过滤器等容易地回收In,大大提高了In的回收率。 In回收方法的特征在于包括粉碎包含铟锡氧化物的废LCD,用酸将粉碎的废LCD中的铟锡氧化物溶解以得到含铟化合物的溶液,使该溶液流入反应器中以进行回收,并且进一步将离子化趋势比In大的金属颗粒加入到反应器中进行回收,使金属颗粒流化,将含铟化合物溶液中包含的In或In合金沉淀到金属颗粒的表面,然后分离沉淀的通过分离装置从金属颗粒中分离出In或In合金,并从液体组分中分离和回收分离出的固体In或In合金。

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