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NATURE DEGRADABLE ADDITIVE COMPOSITION OF POLYOLEFIN THERMOPLASTIC POLYMERS

机译:聚烯烃热塑聚合物的可自然降解的添加剂组成

摘要

An additive composition for biodegradation of a polyolefin-based thermoplastic polymer is provided to ensure stability during the service life and decomposition into non-harmful compounds under natural environment after the use. An additive composition for biodegradation of a polyolefin-based thermoplastic polymer comprises, based on 100 wt% of the total composition: (a) 10-30 wt% of a conventional thermoplastic polymer; (b) 0.3-30 wt% of a biodegradable material comprising at least one material selected from polylactic acid, polycaprolactone, aliphatic polyester, polysaccharides and wax; (c) 0.1-5 wt% of an oxidation accelerator reacting with C-C bonds of the thermoplastic polymer to generate peroxide or hydroperoxide, and comprising at least one material selected from unsaturated fatty acids, liquid edible oil, organic acids and saccharide; (d) 0.1-3 wt% of a catalyst for the oxidation accelerator, comprising at least one material selected from iron stearate and copper stearate; (e) 20-70 wt% of an oxidation accelerating aid selected from the group consisting of clay minerals, calcium carbonate, talc, illite and zeolite; and (f) 0.5-15 wt% of a hydrophilic group-containing polymer comprising at least one of polyvinyl alcohol, polyacrylic acid and polyethylene acrylic acid.
机译:提供了用于基于聚烯烃的热塑性聚合物生物降解的添加剂组合物,以确保使用寿命期间的稳定性以及使用后在自然环境下分解成无害的化合物。基于总组合物的100重量%,用于基于聚烯烃的热塑性聚合物的生物降解的添加剂组合物包含:(a)10-30重量%的常规热塑性聚合物; (b)0.3-30 wt%的可生物降解材料,包括至少一种选自聚乳酸,聚己内酯,脂族聚酯,多糖和蜡的材料; (c)0.1-5 wt%的氧化促进剂,与热塑性聚合物的C-C键反应生成过氧化物或氢过氧化物,并包含至少一种选自不饱和脂肪酸,液态食用油,有机酸和糖的物质; (d)0.1-3重量%的用于氧化促进剂的催化剂,其包含至少一种选自硬脂酸铁和硬脂酸铜的材料; (e)20-70重量%的选自粘土矿物,碳酸钙,滑石,伊利石和沸石的氧化促进助剂; (f)0.5-15wt%的包含聚乙烯醇,聚丙烯酸和聚乙烯丙烯酸中的至少一种的含亲水基的聚合物。

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