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ANTIBACTERIAL OLIGOETHOXY-(4-ORGANOCARBOXYPHENYLOXY)-TETRASILOXANES AND METHOD FOR THEIR PREPARING

机译:抗菌低聚乙氧基-(4-有机羧基苯氧基)-四硅氧烷及其制备方法

摘要

FIELD: organic chemistry, chemical technology.;SUBSTANCE: invention relates to novel chemical compounds that can be used for protection of textile materials from biodamages, and to a method for their synthesis. Invention proposes antibacterial oligoethoxy-(4-organocarboxyphenyloxy)-tetrasiloxanes. These compounds are able to protect textile materials from biodamages and not to be washed off from surface of their fibers in multiple launderings and chemical cleansings. Invention proposes a method for synthesis of claimed oligoethoxy-(4-organocarboxyphenyloxy)-tetrasiloxanes by the condensation reaction of 1 g-mole of decaethoxytetrasiloxane with a desired amount of g-moles of the corresponding 4-organocarboxyphenol representing 4-hydroxybenzoic acid ester in the presence of catalytic amount of tetrachlorosilane at heating and stirring and with simultaneous distillation of formed ethyl alcohol.;EFFECT: improved method of synthesis.;3 cl, 1 dwg, 3 tbl, 7 ex
机译:技术领域本发明涉及可用于保护纺织品材料免受生物损害的新型化合物及其合成方法。本发明提出了抗菌低聚乙氧基-(4-有机羧苯氧基)-四硅氧烷。这些化合物能够保护纺织品材料免受生物损害,并且在多次洗涤和化学清洗中不会从纤维表面被洗掉。本发明提出了一种方法,该方法通过使1克摩尔的十乙氧基四硅氧烷与所需克数摩尔的代表4-羟基苯甲酸酯的相应的4-有机羧基苯酚缩合反应来合成所要求的低聚乙氧基-(4-有机羧基苯氧基)-四硅氧烷。加热和搅拌并同时蒸馏生成的乙醇时存在催化量的四氯硅烷。;效果:改进的合成方法; 3 cl,1 dwg,3 tbl,7 ex

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