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METHOD OF PREPARING CATALYST FOR MIDDLE-TEMPERATURE STEAM-MEDIATED CONVERSION OF CARBON MONOXIDE

机译:一种中温蒸汽介导的一氧化碳转化催化剂的制备方法

摘要

FIELD: carbon monoxide conversion catalysts.;SUBSTANCE: invention relates to a method of preparing catalysts for middle-temperature conversion of carbon monoxide, which can be used in industry when producing nitrogen-hydrogen mix for ammonia synthesis. Preparation of catalyst for middle-temperature conversion of carbon monoxide with water steam, comprising precipitation of iron hydroxide from iron nitrate solution with ammonia-containing solvent, washing of iron hydroxide with water to remove nitrate ions, mixing with calcium and copper ions, mechanical activation of components, molding, drying, and calcination of granules, is characterized by that, in the component mixing step, lanthanum oxide is supplementary added, in which case molar ratio of components is as follows: Fe2O3/CaO/CuO/La2O3 = 1:(0.8-0.9):(0.045-0.08):(0.005-0.01).;EFFECT: increased catalytic activity and more than thrice reduced content of by-products in condensate.;1 tbl, 3 ex
机译:一氧化碳转化催化剂技术领域本发明涉及一种用于一氧化碳中温转化的催化剂的制备方法,该方法可在工业生产氨合成用的氮氢混合物时使用。用于水蒸气一氧化碳中温转化的催化剂的制备,包括用含氨溶剂从硝酸铁溶液中沉淀出氢氧化铁,用水洗涤氢氧化铁以除去硝酸根离子,与钙和铜离子混合,机械活化成分,成型,干燥和煅烧的特征在于,在成分混合步骤中,补充添加氧化镧,在这种情况下,成分的摩尔比为:Fe 2 O 3 / CaO / CuO / La 2 O 3 = 1:(0.8-0.9):( 0.045-0.08):( 0.005-0.01 );效果:提高催化活性,冷凝物中副产物的含量降低三倍以上; 1 tbl,3 ex

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