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METHOD FOR PREPARATION OF POLYALKYLENE THEREPHTHALATES, METHOD TO MANUFACTURE MOULDED POLYALKYLENE THEREPHTHALATE PART AND MOULDED POLYALKYLENETHEREPHTHALATE PART
METHOD FOR PREPARATION OF POLYALKYLENE THEREPHTHALATES, METHOD TO MANUFACTURE MOULDED POLYALKYLENE THEREPHTHALATE PART AND MOULDED POLYALKYLENETHEREPHTHALATE PART
FIELD: chemistry.;SUBSTANCE: method implies: adding molten polyalkylenetherephthalate pre-polymer, which contains 70% (mol) or more of ethylentherephthalate or 1,4-butylenetherephthalate repeating units and has viscosity index [η] within 0.2 to 2 dl/g, via supply port into polymerisation reactor; discharging the pre-polymer introduced through the perforated plate holes; and polymerising pre-polymer under reduced pressure, polymer being let to drop along the open-to-the-outside structural member surface, at temperature from pre-polymer [crystal melting point -10°С] and more to pre-polymer [crystal melting point +30°С] and less under conditions described by formula S1/S2 1, where S1 stands for surface area of polyalkylenetherephthalate being dropped, and S2 stands for area of structural member contacting with polyalkylenetherephthalate.;EFFECT: new method for polyalkylenetherephthalate preparation is suggested.;11 cl, 6 dwg, 10 tbl, 30 ex
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机译:领域:化学方法:该方法意味着:加入熔融的聚对苯二甲酸乙二醇酯预聚物,该聚合物含有70%(摩尔)或更多的对苯二甲酸乙酯或1,4-丁基对苯二甲酸酯重复单元,粘度指数[η]在0.2至2 dl / g,通过进料口进入聚合反应器;排出通过多孔板孔引入的预聚物;并在减压下聚合预聚物,在预聚物[晶体熔点-10°C]及更高的温度下,使聚合物沿着敞开的结构件表面掉落。在式S 1 Sub> / S 2 Sub 1描述的条件下,熔点为+ 30°С和更低,其中S 1 Sub>代表表面积S 2 Sub>代表结构构件与聚对苯二甲酸乙二醇酯接触的面积。;效果:建议制备聚对苯二甲酸乙二醇酯的新方法。; 11 cl,6 dwg,10 tbl,30 ex
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