Provided herein are monocomponent and hybrid catalyst compositions for use in steam-cracking of hydrocarbon feeds to selectively produce light olefins. The catalyst compositions being characterized by a first catalytic component comprising oxides of aluminum, silicon, chromium, and optionally, oxides of monovalent alkaline metals, and further comprising a binder, preferably bentonite clay. Preferably, the catalyst compositions will comprise a catalytic component in accordance with the following formula: (a) SiOSUB2/SUB.(b) A1SUB2/SUBOSUB3/SUB.(c) CrSUB2/SUBOSUB3/SUB(d) alkSUB2/SUBO, with alk being a monovalent alkaline metal, preferably selected from sodium, potassium and lithium. The second catalytic component is selected from a crystalline zeolite or a silica molecular sieve. Also provided in the present invention are methods of making the catalyst compositions.
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机译:本文提供了用于烃进料的蒸汽裂化以选择性地生产轻质烯烃的单组分和杂化催化剂组合物。所述催化剂组合物的特征在于第一催化剂组分包含铝,硅,铬的氧化物,以及任选地一价碱金属的氧化物,并且还包含粘合剂,优选膨润土。优选地,催化剂组合物将包含根据下式的催化组分:(a)SiO 2 SUB>。(b)Al 2 SUB> O 3 SUB (c)Cr 2 SUB> O 3 SUB>(d)烷 2 SUB> O,其中的烷是一价碱金属,最好选自钠,钾和锂。第二催化组分选自结晶沸石或二氧化硅分子筛。本发明还提供了制备催化剂组合物的方法。
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