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Metal-organic framework material of porous, which is based on pyridinone class and pyrroles

机译:基于吡啶酮类和吡咯类的多孔金属有机骨架材料

摘要

The method for producing a metal-organic framework materials porous with at least one organic compound is coordinated to one metal ion, in the presence of one organic compound, the present invention is, at least in the reaction medium at least relates to a method comprising the step of including the oxidation of at least one anode comprising metal corresponding to one metal ion, one organic compound is selected pyrrole, from the group consisting γ- pyridone and α- pyridone least when the two nitrogens and at least, is derived at least from one of the hetero ring that - a ring system monocyclic ring atoms, a bicyclic or polycyclic, said ring system is unsubstituted when the alkyl, phenyl, NH 2, NH (C 1-6 - - alkyl), N (C 1-6 - alkyl) 2, OH, OC 1-6 O and phenyl halogen, C 1-6 independently or whether there - have one or more substituents selected from the group consisting of alkyl, C 1-6 substituents when the - phenyl and alkyl, halogen, NH 2 independently are unsubstituted or substituted, and a more substituents or one selected from the group consisting of alkyl - NH (C 1-6 - alkyl), N (C 1-6 - alkyl) 2, OH, 1-6 OC and O-phenyl.
机译:在一种有机化合物的存在下,至少一种在反应介质中的本发明至少涉及一种方法,该方法包括:将至少一种有机化合物多孔的金属-有机骨架材料与一种金属离子配位的方法。包括以下步骤:至少当衍生至少两个氮和至少两个氮时,氧化至少一个包含对应于一种金属离子的金属的阳极,选自γ-吡啶酮和α-吡啶酮中的一种有机化合物吡咯从一个环系统单环环原子,双环或多环的杂环中,当烷基,苯基,NH 2, NH(C 1-6 --烷基),N(C 1-6 -烷基) 2, OH,OC 1-6 O和苯基卤素,C 1-6 独立地或是否存在-当--时,具有一个或多个选自烷基,C 1-6 取代基的取代基苯基和烷基,卤素,NH 2 独立地未被取代或被取代,并且一个或多个取代基或一个选自烷基-NH(C 1-6 -烷基),N(C 1-6 -烷基) 2, OH, 1-6 OC和O-苯基。

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