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Tantalum oxynitride oxygen reduction electrocatalyst

机译:氧氮化钽氧还原电催化剂

摘要

[Problems] Carbides and many other non-platinum-based compounds are activated and dissolved and cannot be stably present in an acidic electrolyte under conditions of an electrode potential as high as 0.4 V or above, and thus, the application range of these compounds as an electrode catalyst is limited to low electrode potentials. There has been need for development of an electrode catalyst that maintains catalytic activity under these conditions and exhibits improved stability. [Means for Solving Problems] To provide a metal oxynitride electrode catalyst composed of an oxynitride containing at least one transition metal element selected from the group consisting of La, Ta, Nb, Ti, and Zr, the metal oxynitride electrode catalyst being used at a potential of 0.4 V or higher relative to the reversible hydrogen electrode potential in an acidic electrolyte. The metal oxynitride electrode catalyst is useful as an electrode catalyst for electrochemical systems used in acidic electrolytes in the fields of water electrolysis, organic electrolysis, fuel cells, etc.
机译:[问题]碳化物和许多其他非铂基化合物被活化和溶解,并且在电极电位高达0.4 V或更高的条件下不能稳定地存在于酸性电解质中,因此,这些化合物的应用范围为电极催化剂限于低电极电位。需要开发在这些条件下保持催化活性并表现出改善的稳定性的电极催化剂。 [解决问题的手段]提供一种由包含至少一种选自La,Ta,Nb,Ti和Zr的过渡金属元素的氧氮化物组成的金属氧氮化物电极催化剂,该金属氧氮化物电极催化剂在室温下使用。相对于酸性电解质中的可逆氢电极电位为0.4 V或更高。金属氧氮化物电极催化剂可用作水电解,有机电解,燃料电池等领域中用于酸性电解质的电化学系统的电极催化剂。

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