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elastic polymer blends and materials semicrystalline propylene with high glass transition temperature.

机译:弹性聚合物共混物和材料,具有高玻璃化转变温度的半结晶丙烯。

摘要

A composition elastic mixture comprising: (a) from 70% to 95% by weight, based on the total weight of the composition, of a polymer selected from the group consisting of a homopolypropylene and a random copolymer of propylene and at least a comonomer selected from ethylene, alpha-olefin C 4-C 12 and combinations thereof, the polymer having a heat of fusion, determined by DSC, less than 50 J / g as determined by ASTM E-794-95, and a melt index (MI) of less than 7 dg / min as determined by ASTM D1238 (190C, 2.16kg), and containing stereoregular propylene crystallinity, wherein the polymer and other components such as process oil show a single glass transition temperature (Tg1) as measured by DSC between 20 ° C and -50 °; and (b) from 5% to 30% by weight, based on the total weight of the composition, of a hydrocarbon resin having a glass transition temperature measured by increased DSC 20, wherein the hydrocarbon resin has a softening point of between 80 and 180, determined by ASTM E-28 (Revision 1996); (C) wherein (b) it is miscible with (a) and the blend composition shows a single glass transition temperature (Tg2) measured by DSC; with Tg2 higher than Tg1 by at least 1 ° C, and wherein the blend composition has a tension set of less than 20%, determined by ASTM D790.
机译:一种组合物弹性混合物,其包含:(a)基于组合物的总重量,按重量计从70%至95%的聚合物,所述聚合物选自均聚丙烯和丙烯与至少一种共聚单体的无规共聚物。由乙烯,α-烯烃C 4-C 12及其混合物制成,该聚合物的熔解热(通过DSC测定)小于50 J / g(通过ASTM E-794-95测定)和熔体指数(MI)按照ASTM D1238(190C,2.16kg)测定,其分子量小于7 dg / min,并且含有立构规整的丙烯结晶度,其中聚合物和其他组分(例如加工油)的单玻璃化转变温度(Tg1)由DSC测量为20 ℃和-50℃; (b)基于组合物的总重量,按重量计5%至30%的具有通过升高的DSC 20测量的玻璃化转变温度的烃树脂,其中该烃树脂的软化点为80至180 ,由ASTM E-28(1996年修订)确定; (C)其中(b)与(a)可混溶,并且该共混组合物显示通过DSC测量的单一玻璃化转变温度(Tg2); Tg2比Tg1高出至少1°C,且其中共混物组合物的拉伸永久变形小于20%(根据ASTM D790)。

著录项

  • 公开/公告号ES2307038T3

    专利类型

  • 公开/公告日2008-11-16

    原文格式PDF

  • 申请/专利权人 EXXONMOBIL CHEMICAL PATENTS INC.;

    申请/专利号ES20040758316T

  • 发明设计人 DATTA SUDHIN;CURRY CHRISTOPHER LEWIS;

    申请日2004-03-23

  • 分类号C08L23/10;C08L23/02;C08L23/08;C08L23/12;C08L23/14;C08L25/06;C08L57;C08L57/02;C08L91;

  • 国家 ES

  • 入库时间 2022-08-21 19:24:03

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