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SENSITIZING DYE FOR DYE-SENSITIZED SOLAR CELL HAVING EXTENDED Π-ELECTRON CONJUGATED SYSTEM

机译:具有扩展π电子共轭体系的染料敏化太阳能电池的染料敏化

摘要

Disclosed is a low-cost photoelectric converter having high conversion efficiency, which uses dye-sensitized semiconductor fine particles. Also disclosed is a solar cell using such a photoelectric converter. Specifically disclosed is a photoelectric converter wherein a thin film of oxide semiconductor fine particles, which is formed on a substrate, is loaded with a metal complex dye represented by the formula (1) below or a salt thereof. (In the formula (1), rings a, b, c and d may respectively have 1-3 substituents; m represents an integer of 1 or 2; and Z is represented by the following formula (2) or (3).) (In the formula (2), A1 and A2 each represents a hydrogen atom, an optionally substituted aliphatic hydrocarbon residue or an alkoxyl group; and A3 represents a hydrogen atom or an optionally substituted aliphatic hydrocarbon residue. In the formula (3), A4 and A5 each represents a hydrogen atom, an optionally substituted aliphatic hydrocarbon residue or an alkoxyl group; and A6 represents a hydrogen atom or an optionally substituted aliphatic hydrocarbon residue.)
机译:公开了一种具有高转换效率的低成本光电转换器,其使用染料敏化的半导体细颗粒。还公开了使用这种光电转换器的太阳能电池。具体地公开了一种光电转换器,其中在基板上形成的氧化物半导体细颗粒的薄膜中负载有由下式(1)表示的金属络合物染料或其盐。 (在式(1)中,环a,b,c和d可分别具有1-3个取代基; m表示1或2的整数; Z由下式(2)或(3)表示。) (式(2)中,A 1和A 2分别表示氢原子,可被取代的脂肪族烃残基或烷氧基; A 3表示氢原子或可被取代的脂肪族烃残基。 A5代表氢原子,任选取代的脂族烃残基或烷氧基; A6代表氢原子或任选取代的脂族烃残基。

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