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TRIBOCHEMICAL PROCESS FOR OBTAINING ORGANOZEOLITE ADSORBENT OF MYCOTOXINS

机译:霉菌毒素有机沸石吸附剂的摩擦化学过程

摘要

Trybochemical procedure of obtaining organozeolite, mineral adsorbent for the adsorption mycotoxins and its application, as the additive to an animal feed, three degrees crushed zeolite tuff, controlled chemical composition, content 80 % clinoptilolite/heulandite, particles size 150 micrometers, to the known procedure; modificator, quaternary amine with a long chain in a quantity of 0,01-0,10 meq/g tuff is added in turbo mixer with a knives and together mixed with a quickness of 9000 rpm, repeating 2-4 times during the sec; depending on a type and quantity of amine. With this dry procedure reaction between the exchangeable cation on the surface of the tuff, coated with layers of water molecules, and amine by using the high intensity mechanic energy, producing the new component-organozeolite, adsorbent of mycotoxins. Advantage of this invention is mainly economic, because the process of minerals modification is shortening, eliminating the drying and disintegration phases, which are used in known wet process of getting mineral adsorbent mycotoxins. The final product, obtained by trybochemical process is of same quality and has same adsorbing characteristics like products obtained by wet process. Dry process, according this invention is simpler, quicker and cheaper, then the known wet process, both processes give the same product. Organozeolite is added to animal feed directly or in a premix, in the quantity of 0.2 % feed mix.
机译:获得有机沸石,吸附真菌毒素的矿物吸附剂的尝试化学方法及其作为动物饲料添加剂的三度压碎沸石凝灰岩,化学成分可控,斜发沸石/赤铁矿含量为80%,粒径为150微米;改性剂,将带有长链的季胺(量为0.01-0.10 meq / g凝灰岩)添加到带刀的涡轮混合器中,并以9000 rpm的速度混合,在此过程中重复2-4次;取决于胺的类型和数量。通过这种干燥程序,利用高强度机械能,在凝灰岩表面上覆盖有水分子层的可交换阳离子与胺之间发生反应,从而产生了新的成分-有机沸石,即霉菌毒素的吸附剂。本发明的优点主要是经济上的,因为缩短了矿物质的改性过程,消除了干燥和崩解阶段,这是在已知的获得矿物质吸附性真菌毒素的湿法过程中使用的。通过尝试化学方法获得的最终产品与通过湿法获得的产品具有相同的质量和相同的吸附特性。根据本发明的干法更简单,更快速和更便宜,因此与已知的湿法相比,两种方法得到的产物相同。将有机沸石直接或以预混合物的形式添加到动物饲料中,混合量为0.2%。

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