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RADIATION CURABLE AND DEVELOPABLE POLYURETHANE AND RADIATION CURABLE AND DEVELOPABLE PHOTORESIST COMPOSITION CONTAINING THE SAME

机译:辐射可固化可发展的聚氨酯和辐射可固化可发展的光致抗蚀剂组合物

摘要

A polyurethane capable of being cured and developed by the irradiation of radioactive rays, and a photoresist composition containing the polyurethane are provided to improve chemical resistance and heat resistance after the formation of film. A polyurethane capable of being cured and developed by the irradiation of radioactive rays has a carboxylic acid group at the main chain, an acryloyl group and a carboxylic acid group at the side chain, and comprises the random arrangement of the repeating units I, II and III represented by the formulas I, II and III, wherein R1 is a linear or branched alkylene group of C1-12, a C3-8 cyclic alkylene group, a phenylene group, a biphenylene group, a naphthylene group, a xylene group, a toluidinylene group, or -Ph-A-Ph-, and the group may have a C1-6 alkyl group as a substituent; R2 is a divalent aliphatic group capable of at least one OH group; and R3 is a linear or branched C1-6 alkyl group having at least one OH group.
机译:提供能够通过放射线的照射而固化和显影的聚氨酯以及包含该聚氨酯的光致抗蚀剂组合物,以提高膜形成后的耐化学性和耐热性。能够通过放射线照射而固化和显影的聚氨酯在主链上具有羧酸基,在侧链上具有丙烯酰基和羧酸基,并且包括重复单元I,II和II的无规排列。由式I,II和III表示的III,其中R 1为C 1-12的直链或支链亚烷基,C 3-8环状亚烷基,亚苯基,亚联苯基,亚萘基,二甲苯基,甲苯二亚甲基或-Ph-A-Ph-,该基团可以具有碳数1〜6的烷基作为取代基。 R 2为能够至少具有一个OH基的二价脂肪族基团。 R 3为具有至少一个OH基的直链或支链的C 1-6烷基。

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