METHOD FOR PRODUCING 2,3-fullerene 60 -7-phenyl-7-phosphabicyclo 2.2.1 heptane

摘要

A method of preparing 2,3-fullerene [60] -7-phenyl-7-phosphabicyclo [2.2.1] heptane of formula (1), characterized in that the fullerene Svzaimodeystvuet fenilfosfolanom with the general formula, in a molar ratio of C: 0.01 fenilfosfolan: (0,01-0,011), in the presence of a catalyst titanotsendihlorida CpTiCl, taken in an amount of 15-25 mol.% with respect to fullerene C, in toluene as solvent, at a temperature of 140-160 ° C for 4-8 hours.