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SEQUENCE hydroconversion process and the steam reforming to optimize the production of hydrogen fields under development

机译:SEQUENCE加氢转化工艺和蒸汽重整以优化正在开发的氢场的生产

摘要

1. A method for processing a hydrocarbon feedstock comprising a sequence of first implemented upstream from a hydroconversion process, comprising at least one reactor, the reaction or reactions occurring within the reactor, and introducing the above effect, at least one solid phase, by at least one liquid phase and at least one gas phase and a second process carried out downstream of the steam reforming, comprising at least one reactor, wherein the above-mentioned process is conducted upstream carried out in a suspension and / or in a fluidized bed, and the above process is implemented downstream comprises a first conversion step, at least partially, hydrocarbons heavier than methane into methane, called step pre-reforming, and the reaction or reactions occurring inside the reactor above process carried out downstream, produce reactant hydrogen necessary for chemical reactions of the first protsessa.2. A method according to claim 1, wherein the process is conducted upstream zone comprises contacting the liquid loading, gaseous and solid loading chastits.3. A method according to claim 1 or 2, wherein the solid particles used in the slurry reactor, the catalyst particles are continuously introduced into the reactor with fresh feed, and formed from soluble cell comprising one or more metals capable of sulfonated under sposoba.4 . A method according to claim 1 or 2, operating in the fluidized bed, which uses a supported catalyst comprising at least one metal element.5. A method according to claim 1 or 2, wherein the solid catalyst particles comprise molibden.6. The method of claim 1, wherein the hydrocarbon feed has a heavy metal content of more than 5 hours. / Mln.7. A method according to claim 6, wherein the hydrocarbon feed has a heavy metal content in a range of 20 to 1000 hr. / Mln.8. A method according to claim 6 or 7, wherein the hydrocarbon feed has a heavy metal content in a range from 50 to 500 hrs. / Mln.9. A method according to claim 6 or 1, wherein the hydrocarbon feedstock is selected from the waste released into the atmosphere, vacuum residues from direct distillation, deasphalted residues, residues originating from the conversion process, crude oils, bitumen extracted from deposits of bituminous sands or oil shale, liquid products resulting from the hydroconversion in a fixed bed, the liquid products produced during the hydrotreatment of heavy oil in the fluidized bed, oils, deasphalted solvent, asphalt, either alone or diluted with a hydrocarbon fraction or a mixture of hydrocarbon fractions selected from the group formed by oils of light fraction oils the heavy fraction, decanted oils, residual fractions of cracking processes, which may contain a suspension of fine catalyst particles and gas oil distillates, gas oil fractions and a heavy gas oil derived from a catalytic cracking process, aromatic extracts obtained under the manufacture of lubricating oils, waste processing biomass singly or smesi.10. A method according to claim 6 or 7, wherein the hydrocarbon feed is selected from liquid hydrocarbons resulting from liquefaction uglya.11 stone. A method according to claim 6 or 7, wherein the operating conditions of the first treatment zone hydrocarbons (upstream) are: total pressure 80 to 500 bar hydrogen partial pressure ranges from 10 to 500 bar, a temperature of 300 to 600 ° C, wherein the contact is carried out for a time varying from 5 minutes to 20 ch.12. A method according to claim 6 or 7, wherein the operating conditions of the second treatment zone hydrocarbons (downstream) the following: pressure of 10 to 50 bar absolute and the temperature is increased as approaching the furnace konversii.13. A method according to claim 6 or 7, wherein along with the loading zone is recycled to the reaction of the residual fraction flows through fractional distillation separation downstream of the last reaction zone of a process performed upstream, with recycle to the reaction product is in this case part liquid obtained at the bottom of the column.
机译:1。一种用于处理烃原料的方法,其包括在加氢转化过程的上游首先实施的序列,该序列包括至少一个反应器,该反应或多个反应在该反应器内发生,并通过在至少一个固相处引入上述效果。在蒸汽重整的下游进行的至少一种液相和至少一种气相和第二种方法,包括至少一个反应器,其中上述方法在上游进行,在悬浮液和/或流化床中进行,并且上述方法在下游实施,包括第一转化步骤,该步骤至少部分地将比甲烷重的碳氢化合物转化为甲烷,称为步骤预重整,并且在上述方法的反应器内发生的反应在下游进行,产生所需的反应物氢。第一个protsessa的化学反应2。 2.根据权利要求1所述的方法,其特征在于,所述过程在上游区域进行,包括使液体负荷,气体负荷和固体负荷负荷接触。3。 3.根据权利要求1或2所述的方法,其中将所述淤浆反应器中使用的固体颗粒,所述催化剂颗粒与新鲜进料连续地引入所述反应器中,并且由包含一种或多种能够在sposoba.4下进行磺化的金属的可溶性小室形成。 3.根据权利要求1或2所述的方法,其在流化床中操作,所述流化床使用包含至少一种金属元素的负载型催化剂。 3.根据权利要求1或2所述的方法,其中,所述固体催化剂颗粒包含钼6。 2.权利要求1的方法,其中烃进料的重金属含量大于5小时。 / Mln.7。 7.根据权利要求6的方法,其中烃进料的重金属含量为20-1000小时。 / Mln.8。 8.根据权利要求6或7所述的方法,其中所述烃进料的重金属含量为50至500小时。 / Mln.9。 2.根据权利要求6或1所述的方法,其中,所述烃原料选自释放到大气中的废物,来自直接蒸馏的真空残余物,脱沥青的残余物,源自转化过程的残余物,原油,从沥青砂的沉积物中提取的沥青,或油页岩,固定床加氢转化产生的液体产品,流化床重油加氢处理过程中产生的液体产品,油,脱沥青溶剂,沥青,可单独使用或用烃馏分或烃馏分的混合物稀释选自轻质馏分油,重质馏分油,can析油,裂化过程的残余馏分组成的组,裂化过程的残余馏分可能包含催化剂细颗粒和粗柴油馏分的悬浮液,粗柴油馏分和源自催化作用的重质粗柴油裂解过程,在润滑油生产下获得的芳烃提取物,废物处理生物质smesi 10。 8.根据权利要求6或7所述的方法,其中,所述烃进料选自由液化uglya.11石头产生的液态烃。 8.根据权利要求6或7所述的方法,其中,所述第一处理区碳氢化合物(上游)的操作条件为:总压80至500bar,氢分压为10至500bar,温度为300至600℃,其中接触时间从5分钟到20ch.12不等。 8.根据权利要求6或7所述的方法,其中,所述第二处理区的烃的操作条件(下游)如下:绝对压力为10至50bar,并且随着接近所述炉,温度升高。 8.根据权利要求6或7所述的方法,其中,与所述装载区一起再循环到所述反应中,所述残余馏分在上游进行的方法的最后反应区的下游通过分馏分离从下游进行分馏,其中再循环到所述反应产物中。外壳部分液体从塔底获得。

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