Hydrocracking catalysts for vacuum gas oil demetallized AND MIXES

摘要

1. the catalyst u0434u043bu00a0 processing of hydrocarbon mixtures VGO / DMO to catalytic u043fu0440u0435u0432u0440u0430u0449u0435u043du0438u00a0 mixture VGO / DMO useful hydrocarbon products with shorter the chain, and the catalyst includes;the catalytic material is a material comprising u043cu0435u0437u043eu043fu043eu0440u0438u0441u0442u044bu0439 mcm - 41;catalytic metal which is catalytic material carrier, and;metal promoter on u043au0430u0442u0430u043bu0438u0442u0438u0447u0435u0441u043au043eu043c material is medium, a u0434u043bu00a0 u043fu043eu0432u044bu0448u0435u043du0438u00a0 catalytic conversion;where the catalytic material vehicle with catalytic metal and metal - u043fu0440u043eu043cu043eu0442u043eu0440u043eu043c u00a0u0432u043bu00a0u0435u0442u0441u00a0 functional u0434u043bu00a0 order to catalytically convert VGO / DMO in a. u043bu0435u0432u043eu0434u043eu0440u043eu0434u043du044bu0435 products with shorter carbon chain.;2. catalyst for catalytic component 1 where the metal u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a molybdenum and a metal promoter u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a nickel.;3. catalyst for the catalytic material 1 or 2, where the vehicle includes u0443u043bu044cu0442u0440u0430u0441u0442u0430u0431u0438u043bu044cu043du044bu0439 y - u0446u0435u043eu043bu0438u0442.;4. catalyst for 1 or 2, where the catalytic material is an u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 only u043cu0435u0437u043eu043fu043eu0440u0438u0441u0442u044bu0439 material mcm - 41.;5. catalyst for 1 or 2, where the catalytic material which includes, u0446u0435u043eu043bu0438u0442.;6. catalyst for 1 or 2, where the catalytic material which comprises amorphous aluminosilicate.;7. catalyst for 1 or 2, where a catalytic material selected from a group u0441u043eu0441u0442u043eu00a0u0449u0435u0439 of u0443u043bu044cu0442u0440u0430u0441u0442u0430u0431u0438u043bu044cu043du043eu0433u043e y - u0446u0435u043eu043bu0438u0442u0430, u043cu0435u0437u043eu043fu043eu0440u0438u0441u0442u043eu0433u043e material mcm - 41 - u0446u0435u043eu043bu0438u0442u0430, amo u0440u0444u043du043eu0433u043e u0430u043bu044eu043cu043eu0441u0438u043bu0438u043au0430u0442u0430 and their combinations.;8. catalyst for 2, where at least a part of the u043du0438u043au0435u043bu00a0 is present in the form of sulfide u043du0438u043au0435u043bu00a0.;9. catalyst for catalytic u043cu0435u0442u0430u043bu043bu043eu043au043eu043cu043fu043eu043du0435u043du0442 1 is selected from the group u0441u043eu0441u0442u043eu00a0u0449u0435u0439 of molybdenum, tungsten and their combinations, and where the metal promoter selected from the group. u0441u043eu0441u0442u043eu00a0u0449u0435u0439 of u043du0438u043au0435u043bu00a0, cobalt and their combinations.;10. catalyst for p.9, where at least a part of the u043du0438u043au0435u043bu00a0 is present in the form of sulfide u043du0438u043au0435u043bu00a0.;11. catalyst for p.9, where at least part of the cobalt is present in the form of cobalt sulfide.;12. the catalyst in any of the u043fu043f.1, 2 and 8 - 11, where u0443u0433u043bu0435u0432u043eu0434u043eu0440u043eu0434u043du0430u00a0 mixture VGO / DMO contains at least 10% DMO volume.;13. the catalyst in any of the u043fu043f.1, 2 and 8 - 11, where u0443u0433u043bu0435u0432u043eu0434u043eu0440u043eu0434u043du0430u00a0 mixture VGO / DMO contains at least 15% DMO volume.;14. the catalyst in any of the u043fu043f.1, 2 and 8 - 11, where the catalytic carrier with the catalytic metal, and metal - u043fu0440u043eu043cu043eu0442u043eu0440u043eu043c by co impregnation.;15. the catalyst in any of the u043fu043f.1, 2 and 8 - 11, where the catalytic carrier with the catalytic metal, and metal - u043fu0440u043eu043cu043eu0442u043eu0440u043eu043c by sequential impregnation.;16. method of u043fu0440u0435u0432u0440u0430u0449u0435u043du0438u00a0 u0442u00a0u0436u0435u043bu044bu0435 u0434u0435u043cu0435u0442u0430u043bu043bu0438u0437u0438u0440u043eu0432u0430u043du043du043eu0439 oil containing hydrocarbons, including stage;u0432u0432u0435u0434u0435u043du0438u00a0 u0442u00a0u0436u0435u043bu044bu0435 hydrocarbons containing u0434u0435u043cu0435u0442u0430u043bu043bu0438u0437u0438u0440u043eu0432u0430u043du043du043eu0439 oil cycle reactor;u0432u0432u0435u0434u0435u043du0438u00a0 catalyst in the stage of reactor and catalyst includes:;the catalytic material is a material comprising u043cu0435u0437u043eu043fu043eu0440u0438u0441u0442u044bu0439 mcm - 41;the catalytic metal u043fu0440u043eu043fu0438u0442u044bu0432u0430u044eu0449u0438u0439 catalytic material carrier, and;metal promoter on u043au0430u0442u0430u043bu0438u0442u0438u0447u0435u0441u043au043eu043c material is medium, a u0434u043bu00a0 u043fu043eu0432u044bu0448u0435u043du0438u00a0 catalytic conversion;where the catalytic material vehicle with catalytic metal and metal - u043fu0440u043eu043cu043eu0442u043eu0440u043eu043c u00a0u0432u043bu00a0u0435u0442u0441u00a0 functional u0434u043bu00a0 order to catalytically convert, on the edge of her as part of the u0434u0435u043cu0435u0442u0430u043bu043bu0438u0437u0438u0440u043eu0432u0430u043du043du043eu0439 oil in petroleum products with shorter carbon chain.;17. way on p.16, where catalytic component, a metal u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 molybdenum and a metal promoter u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 a nickel.;18. way on p.16 or 17, where the catalytic material which includes u0443u043bu044cu0442u0440u0430u0441u0442u0430u0431u0438u043bu044cu043du044bu0439 y - u0446u0435u043eu043bu0438u0442.;19. way on p.16 or 17, where the catalytic material is an u043fu0440u0435u0434u0441u0442u0430u0432u043bu00a0u0435u0442 only u043cu0435u0437u043eu043fu043eu0440u0438u0441u0442u044bu0439 material mcm - 41.;20. way on p.16 or 17, where the catalytic material which includes, u0446u0435u043eu043bu0438u0442.;21. way on p.16, or 17, where the catalytic material which comprises amorphous aluminosilicate.;22. way on p.16 or 17, where the catalytic material selected from a group u0441u043eu0441u0442u043eu00a0u0449u0435u0439 of u0443u043bu044cu0442u0440u0430u0441u0442u0430u0431u0438u043bu044cu043du043eu0433u043e y - u0446u0435u043eu043bu0438u0442u0430, u043cu0435u0437u043eu043fu043eu0440u0438u0441u0442u043eu0433u043e material mcm - 41 - u0446u0435u043eu043bu0438u0442u0430, u0430u043cu043eu0440u0444u043du043e the u0430u043bu044eu043cu043eu0441u0438u043bu0438u043au0430u0442u0430 and their combinations.;23. way on p.16 or 17, where the catalytic component is selected from the metal group, u0441u043eu0441u0442u043eu00a0u0449u0435u0439 of u043du0438u043au0435u043bu00a0, cobalt and their combinations, and where the metal promoter selected from a group, sos u0442u043eu00a0u0449u0435u0439 of molybdenum, tungsten and their combinations.;24. way on p.16 or 17, where u0443u0433u043bu0435u0432u043eu0434u043eu0440u043eu0434u043du0430u00a0 mixture VGO / DMO contains at least 10% DMO volume.;25. way on p.16 or 17, where u0443u0433u043bu0435u0432u043eu0434u043eu0440u043eu0434u043du0430u00a0 mixture VGO / DMO contains at least 15% DMO volume.;26. method for the p.23, where at least a part of the u043du0438u043au0435u043bu00a0 is present in the form of sulfide u043du0438u043au0435u043bu00a0.;27. method for the p.23, where at least part of the cobalt is present in the form of cobalt sulfide.;28. way on any of the u043fu043f.16, 17 or 27, where the catalytic carrier with the catalytic metal, and metal - u043fu0440u043eu043cu043eu0442u043eu0440u043eu043c by co impregnation.;29. way on any of the u043fu043f.16, 17 or 27, where the catalytic carrier with the catalytic metal, and metal - u043fu0440u043eu043cu043eu0442u043eu0440u043eu043c by sequential impregnation.;30. way on any of the u043fu043f.16, 17 or 27, further including a phase u043fu043eu0434u0434u0435u0440u0436u0430u043du0438u00a0 pre-determined temperature in the reactor.;31. method for pre u0437u0430u0434u0430u043du043du0430u00a0 p.30, where the temperature is at least 390C.;32. method for pre u0437u0430u0434u0430u043du043du0430u00a0 p.30, where the temperature is at least 400C.