METHOD FOR PREPARATION OF 2,4,6,8,10,12-HEXANITRO-2,4,6,8,10,12-HEXAAZATETRACYCLO5,5,0,0^3,11,0^5,9DODECANE

摘要

FIELD: chemistry.;SUBSTANCE: invention refers to the method for preparation of the high-efficiency explosive 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,0^3,11, 0^5'9]dodecane. 4,10-dibenzyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,0^3,11,0^5,9]dodecane is hydrogenated in the mixture of formic and acetic acids, then obtained mixture of 4,10-diformyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,0^3,11,0^5,9]dodecane and 4-formyl-2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazatetracyclo[5,5,0,0^3,11,0^5,9]dodecane is nitrated in the crystalline form or in the mixture of formic and acetic acids.;EFFECT: substantial enhancing of the process feasibility and safety together with increase of the target product yield.;1 cl, 7 ex, 2 tbl