Detergent, useful to improve the graying-inhibiting action during washing of textile products, comprises anti-grey polycarbonate, polyurethane and polyurea-polyorganosiloxane compound and a surfactant

摘要

Detergent comprises an anti-grey polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compound (I) or its acid addition compound and/or salts and a surfactant and further ingredients of washing- and cleaning agents. Detergent comprises an anti-grey polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compound of formula (-Y 1-A-(C=O)-A-) (I) or its acid addition compound and/or salts and a surfactant and further ingredients of washing- and cleaning agents. Either A : S, O or NR 1; and Y 1bivalent to polyvalent, preferably tetravalent, optionally saturated or aromatic up to 1000C hydrocarbon containing one or more NR 2, N +R 2R 3(both preferred), O, (CO), NH, 2-1000 polyorganosiloxane unit with silicon atom (optionally substituted), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); or Y 1A : nitrogen containing heterocyclic ring; R 1H, optionally saturated or aromatic up to 40C hydrocarbon containing one or more O, (CO), NH, NR 2, preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); R 2optionally saturated, aromatic up to 40C hydrocarbon containing one or more O, (CO), NH, preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); and R 3optionally saturated, aromatic up to 100C-hydrocarbon containing one or more O, (CO), NH, a bivalent residue, which forms cyclic structures within the Y 1, preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000). Provided that: in formula (I) A, Y 1, R 1, R 2, R 3are not same when at least one of the residues of Y 1is polyorganosiloxane unit with 2-1000 silicon atom. An independent claim is included for the detergent comprising surfactant and further ingredients of washing- and cleaning-agent comprising [1,3]-dioxolan-2-one compound of formula (IV) or [1,3]-diazepan-2-one compound of formula (V) and/or a polymer, which is obtained by the reaction of a polymer substrate (that modifies the functional groups of hydroxy-, primary and secondary amino- group) with (IV) or (V). R : 1-12C-alky; X : -CO-CH=CH 2, -CO-C(CH 3)=CH 2, -CO-O-aryl, 2-6C-alkylene-SO 2-CH=CH 2or -CO-NH-R1a; R1a : 1-30C-alkyl, 1-30C-haloalkyl, 1-30C-hydroxyalkyl, 1-6C-alkyloxy-1-30C-alkyl, 1-6C-alkylcarbonyloxy-1-30C-alkyl, amino-1-30C-alkyl, mono- or di(1-6C-alkyl)amino-1-30C-alkyl, ammonio-1-30C-alkyl, polyoxyalkylene-1-30C-alkyl, polysiloxanyl-1-30C-alkyl, (meth)acryloyloxy-1-30C-alkyl, sulfono-1-30C-alkyl, phosphono-1-30C-alkyl, di(1-6C-alkyl)-phosphono-1-30C-alkyl, phosphonato-1-30C-alkyl, di(1-6C-alkyl) phosphonato-1-30Calkyl or a saccharide; and k : greater than 0. Provided that: in formula (IV) when k is 1, X has the above variable or when k is greater than 1, X is: (i) polyamine bounded with ((CO)-NH) or (ii) polymer skeleton bounded with (CO)-, NH-2-6C-alkylene-O(CO)- or (CO)-O-2-6C-alkylene-O(CO)- or (iii) polymer skeleton bounded with (CO)-polysiloxanyl-1-30C-alkyl-groups. [Image] .