Use of polycarbonate, polyurethane and/or polyurea polyorganosiloxane compounds or their acid addition compound and (1,3)-dioxolan-2-one or (1,3)-diazepan-2-one compound and polymer for fixing fragrance on hard and/or soft surfaces

摘要

Use of polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds (I) or its acid addition compound and/or salts and (1,3)-dioxolan-2-one compound (IV) or (1,3)-diazepan-2-one compound (V) and a polymer, which is obtained by the reaction of a polymer substrate (that modifies the functional groups of hydroxy-, primary and secondary amino-group) with (IV) or (V), for fixing fragrances on hard- and/or soft surfaces, is claimed. Use of polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compound of formula (-Y 1-A-(C=O)-A-) (I) or its acid addition compound and/or salts and (1,3)-dioxolan-2-one compound of formula (IV) or (1,3)-diazepan-2-one compound of formula (V) and polymer which is obtained by the reaction of a polymer substrate (that modifies the functional groups of hydroxy-, primary and secondary amino- group) with (IV) or (V), for fixing fragrances on hard- and/or soft surfaces, is claimed. Either A : S, O or NR 1; and Y 1bivalent to polyvalent, preferably tetravalent, optionally saturated or aromatic up to 1000C hydrocarbon containing one or more NR 2, N +R 2R 3 (both preferred), O, (CO), NH, 2-1000 polyorganosiloxane unit with silicon atom (optionally substituted), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); or Y 1A : nitrogen containing heterocyclic ring; R 1H, optionally saturated or aromatic up to 40C hydrocarbon containing one or more O, (CO), NH, NR 2, ), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); R 2optionally saturated, aromatic up to 40C hydrocarbon containing one or more O, (CO), NH, ), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); R 3optionally saturated, aromatic up to 100C-hydrocarbon containing one or more O, (CO), NH, a bivalent residue, which forms cyclic structures within the Y 1, ), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); R : 1-12C-alky; X : CO-CH=CH 2, CO-C(CH 3)=CH 2, CO-O-aryl, 2-6C-alkylene-SO 2-CH=CH 2 or CO-NH-R1a; R1a : 1-30C-alkyl, 1-30C-haloalkyl, 1-30C-hydroxyalkyl, 1-6C-alkyloxy-1-30C-alkyl, 1-6C-alkylcarbonyloxy-1-30C-alkyl, amino-1-30C-alkyl, mono- or di(1-6C-alkyl)amino-1-30C-alkyl, ammonio-1-30C-alkyl, polyoxyalkylene-1-30C-alkyl, polysiloxanyl-1-30C-alkyl, (meth)acryloyloxy-1-30C-alkyl, sulfono-1-30C-alkyl, phosphono-1-30C-alkyl, di(1-6C-alkyl)-phosphono-1-30C-alkyl, phosphonato-1-30C-alkyl, di(1-6C-alkyl) phosphonato-1-30Calkyl or a saccharide; and k : greater than 0. Provided that: in formula (I) A, Y 1, R 1, R 2, R 3 are not same when at least one of the remainders of Y 1 is polyorganosiloxane unit with 2-1000 silicon atom; in formula (IV) when k is 1, X has the above variable or when k is greater than 1 X is: (i) polyamine bounded with ((CO)-NH) or (ii) polymer skeleton bounded with (CO)-, NH-2-6C-alkylene-O(CO)- or (CO)-O-2-6C-alkylene-O(CO)- or (iii) polymer skeleton bounded with (CO)-polysiloxanyl-1-30C-alkyl-groups. Independent claims are included for: (1) fixing the fragrances comprising reacting the surface of the fragrance and (I) or its acid addition compound and/or salts or (IV) and/or (V) and/or the polymer, in the presence of water for 2-90 minutes at 95[deg] C; and (2) a washing- or cleaning agent comprising the fragrances, preferably aroma materials of ester, ether, aldehyde, ketone, alcohols and/or hydrocarbons and (I), or its acid addition compound and/or salts or (IV) or (V) and/or the polymer. [Image].