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Delamination clay - polyolefine nano- composite formation method

机译:分层粘土-聚烯烃纳米复合材料的形成方法

摘要

The cation exchange stratified filling up material of 1 where it is selected from the group which consists of the cation exchange stratified chemical compound other than the cation exchange stratified inorganic silicate and the silicate types being processed acid at least, the nano- composite formation method of being due to the olefin polymerization which the catalyst which is activated for the olefin polymerization to the occasion where it contacted with the bulking agent where the stratified structure was destroyed, said acid was processed is mixed. Olefin, when (a) also the alkyl aluminum under non- existing of the catalyst or (b) the activated possible catalyst is poly- alkyl metal chemical compound, also the alkyl aluminum under existing of the catalyst, the description above contacts with the catalyst/bulking agent blend which is activated, the polyolefine and acid forms the nano- composite which includes the bulking agent which was processed. With feature of specification, high fill nano- composite master batch is manufactured making use of the bulking agent of ten kind of quantity which the nano- composite forms 30 weight % at least. Next, the aforementioned master batch blending or more the olefin polymer of 1 types or 2 types at the specified quantity, it is possible to obtain the nano- composite which possesses the fill of desire. The bulking agent is the clay desirably, you can list the montmorillonite as the example. The catalyst is the non metallocene catalyst desirably, it is the nickel complex which is most desirable, possesses the iminokarubokisamidato ligand.
机译:1的阳离子交换层状填充材料,选自由阳离子交换层状无机硅酸盐以外的阳离子交换层状化合物和至少被酸处理的硅酸盐类型组成的组,由于烯烃聚合反应中活化的催化剂与破坏层状结构的填充剂接触而被烯烃聚合,所以将所述酸进行混合。烯烃,当(a)催化剂不存在下的烷基铝或(b)可能活化的催化剂是聚烷基金属化合物时,也存在催化剂下的烷基铝,上述说明与催化剂接触活化的/填充剂共混物,聚烯烃和酸形成包含已加工的填充剂的纳米复合材料。具有规格特点,利用纳米复合材料至少形成30重量%的十种数量的填充剂制造高填充纳米复合材料母料。接下来,以指定的量通过上述母料共混一种或两种以上的烯烃聚合物,可以获得具有所需填充量的纳米复合材料。填充剂理想地是粘土,您可以列举蒙脱土作为例子。催化剂理想地是非金属茂催化剂,最需要的是镍配合物,具有亚氨基氨基甲酸酯基氨基甲酸酯基配体。

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