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Method for manufacturing carbon nanostructures having minimal surface functional groups

机译:具有最小表面官能团的碳纳米结构的制造方法

摘要

Carbon nanostructures are formed from a carbon precursor and catalytic templating nanoparticles. Methods for manufacturing carbon nanostructures generally include (1) forming a precursor mixture that includes a carbon precursor and a plurality of catalytic templating particles, (2) carbonizing the precursor mixture to form an intermediate carbon material including carbon nanostructures, amorphous carbon, and catalytic metal, (3) purifying the intermediate carbon material by removing at least a portion of the amorphous carbon and optionally at least a portion of the catalytic metal, and (4) heat treating the purified intermediate carbon material and/or treating the purified intermediate carbon material with a base to remove functional groups on the surface thereof. The removal of functional groups increases the graphitic content of the carbon nanomaterial and decreases its hydrophilicity.
机译:碳纳米结构由碳前驱体和催化模板纳米颗粒形成。用于制造碳纳米结构的方法通常包括(1)形成包括碳前体和多个催化模板颗粒的前体混合物,(2)碳化前体混合物以形成包括碳纳米结构,无定形碳和催化金属的中间碳材料。 ;(3)通过除去至少一部分无定形碳和可选地至少一部分催化金属来纯化中间碳材料,以及(4)对纯化的中间碳材料进行热处理和/或对纯化的中间碳材料进行处理用碱除去表面上的官能团。官能团的去除增加了碳纳米材料的石墨含量并降低了其亲水性。

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