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PRODUCTION OF A MATERIAL COMPRISING A MIXTURE OF NOBLE METAL NANOPARTICLES AND RARE-EARTH OXIDE NANOPARTICLES

机译:包含贵金属纳米颗粒和稀土氧化物纳米颗粒混合物的材料的生产

摘要

The invention relates to the production of a material comprising a mixture of noble metal nanoparticles and rare-earth oxide nanoparticles. The process comprises the following successive steps:a) production of a metal alloy comprising at least one noble metal chosen from the group comprising the elements Ru, Rh, Ir, Ag, Au, Pd, Pt, Ni and Cu and at least one rare earth chosen from the group comprising the elements La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y and Sc, said alloy containing a crystalline phase the rare earth content of which is greater than 10 at % and the noble metal content of which is between 25 and 75 at %; andb) oxidation, in an oxidizing atmosphere, of the metal alloy obtained during step a).;The subject of the invention is also a composite comprising a mixture of noble metal nanoparticles and rare-earth oxide nanoparticles and to the use of such a composite, in particular for catalysis.
机译:本发明涉及包含贵金属纳米颗粒和稀土氧化物纳米颗粒的混合物的材料的生产。该过程包括以下连续步骤: a)生产一种金属合金,该金属合金包括至少一种选自以下元素的贵金属:Ru,Rh,Ir,Ag,Au,Pd,Pt,Ni和Cu以及至少一种稀土元素从包括元素La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y和Sc的组中选择,所述合金包含晶相稀土含量其中大于10原子%且贵金属含量在25至75原子%之间;和 b)在氧化气氛中,将步骤a)中获得的金属合金氧化。 ;本发明的主题还是一种包含贵金属纳米颗粒和稀土氧化物纳米颗粒的混合物的复合物,并且涉及这种复合物的用途,特别是用于催化。

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