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PRODUCTION OF A MATERIAL COMPRISING A MIXTURE OF NOBLE METAL NANOPARTICLES AND RARE-EARTH OXIDE NANOPARTICLES

机译:包含贵金属纳米颗粒和稀土氧化物纳米颗粒混合物的材料的生产

摘要

The invention relates to the production of a material comprising a mixture of noble metal particles and rare-earth oxide nanoparticles. The process comprises the following successive steps: a) production of a metal alloy comprising at least one noble metal, chosen from the group comprising the elements Ru, Rh, Ir, Ag, Au, Pd, Pt, Ni and Cu, and at least one rare earth chosen from the group comprising the elements La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Y and Sc, said alloy containing a crystallized phase, the rare-earth content of which is greater than 10 at% and the noble metal content of which is between 25 and 75 at%; and b) oxidation in an oxidizing atmosphere of the metal alloy obtained during step a). The subject of the invention is also a material comprising a mixture of noble metal nanoparticles and rare-earth oxide nanoparticles, and also the use of such a material, especially for catalysis.
机译:本发明涉及包含贵金属颗粒和稀土氧化物纳米颗粒的混合物的材料的生产。该方法包括以下连续步骤:a)生产包含至少一种贵金属的金属合金,所述贵金属选自元素Ru,Rh,Ir,Ag,Au,Pd,Pt,Ni和Cu,以及至少一种选自元素La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu,Y和Sc的一种稀土元素,所述合金包含结晶相,其稀土含量大于10 at%,贵金属含量在25至75 at%之间; b)在步骤a)中获得的金属合金的氧化气氛中的氧化。本发明的主题还是一种包含贵金属纳米颗粒和稀土氧化物纳米颗粒的混合物的材料,以及这种材料的用途,特别是用于催化。

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