首页> 外国专利> - Aunt 1,5,8 1H - 2 - - - - 2.2 - triaza naftalen dioxides with herbicidal activity

- Aunt 1,5,8 1H - 2 - - - - 2.2 - triaza naftalen dioxides with herbicidal activity

机译:-1,5,8姨妈1H-2----2.2-具有除草活性的Triaza naftalen二氧化物

摘要

This also relates to processes for preparing the compounds of formula (1), Intermediates used in the preparation of compounds of the formula (1), Methods to control plants and compositions comprising the compounds of formula (1).Claim 1: a compound of the formula (1) wherein R1 and R2 are independently Hydrogen, c1-4 alkyl, haloalquilo c1-4, Halo, cyano, Hydroxy, alkoxy c1-4, Alquiltio c1-4, aryl or aryl substituted by one to five R6, which may be the same or different or heteroaryl heteroaryl, or Replaced by one to five R6, which may be the same or different; R3 is Hydrogen, alkyl C1 - 10Haloalquilo alquenilo C1 - C2 - 4, 10, haloalquenilo alquinilo C2 C2 - 4, - 10, - 4 haloalquinilo C2, C3 C3 cicloalquil cycloalkyl - 10, 10 - 6 - alkoxy alkyl C1, C1 C1 - 6 - 10 - alkyl -, cianoalquil C1 - 10 10 - - - alcoxicarbonil C1 C1 alkyl - 6 -, N - alkyl c1-3 alkyl - Aminocarbonyl - C1 - 6 -, N, N - (c1-3 alkyl) - aminocarboni L - alkyl C1 - 6 -Aryl alkyl - or aryl - C1 - 6 - 6 C1 alkyl aryl - in which the rest is replaced by one to three R7, which may be identical or different, or heterociclil - C1 - 6 - alkyl or alkyl heterociclil - C1 - 6 - in which the rest heterociclilo is replaced by one to three R7, which may be the same or different; R4 is aryl or aryl substituted by one to five R8, which may be the same or differentOr or heteroaryl heteroaryl substituted by one to four R8, which may be the same or different; R5 is Hydroxy or a group that can be metabolized in a Hydroxy Group; each of R6, R7 and R8 is independently, halociano C1 alkyl, Nitro, - 10, - 4 alquenilo haloalquilo C1, C2 - 10 alquinilo C2 10, Hydroxy, alkoxy C1 - 10, haloalcoxi c1-4 alkoxy, C1 - C3 c1-4 alkyl, cycloalkyl - 7Cicloalcoxi C3 C3 - 7 - 7, cicloalquil c1-4 alkyl, alkoxy cicloalquil C1 - C3 - 7 - 4 - 6 - C1 alkyl carbonyl, Formilo (c1-4 alkoxy carbonyl) - 4 - Alquiltio alquilcarboniloxi C1, C1 -, 10 -, 4 - haloalquiltio C1, C1 alquilsulfinil haloalquilsulfinil C1 - - 10 -, 4 -, 10 - haloalquilsulfonil alquilsulfonil C1, C1 - 4 - AM No, alquilamino C1 - 10 -, di - alquilamino C1 - C10, alquilcarbonilamino C1 - 10 -Aryl or aryl substituted by one to three R13, which may be identical or different, or heteroaryl heteroaryl substituted by one to three R13, which may be identical or different, aryl alkyl - or aryl c1-4 alkyl C1 - 4 - aryl - in which the rest is replaced by one to three R13. May be equal to Or different- heteroaryl heteroaryl alkyl c1-4 alkyl - or - C1 - 4 - in which the rest is heteroaryl substituted by one to three R13, which may be identical or different, ariloxi - or ariloxi - replaced by one to three R13, which may be identical or different, heteroariloxi - substituted by one or heteroariloxi TR R13 is, which may be identical or different, ariltio - or ariltio - replaced by one to three R13,That may be the same or different, or heteroariltio - or heteroariltio - replaced by one to three R13, which may be identical or different, and each R13 is independently alkyl, cyano, Nitro, haloalquilo C1 C1 - 6, 6 - alkoxy - or C1 6 or a Salt or n-oxide thereof.Claim 7: a compound of the formula (2) in which R1, R2, and R4 are as defined in claim 1, and R16 is alkyl C1 - 6; or a Salt or n-oxide thereof.Claim 8: Another group are the compounds of formula (1) wherein R1, R2, and R4 are as defined in claim 1; R3 is alkyl alquenilo C1 - C2 - 10, 10, 10 alquinilo C2 - C3 - 10, cycloalkyl, cicloalquil C1 C3 alkyl - 6 - 10 - alkoxy alkyl C1, C1 - 6 - 10 -, 10 - alkoxy - cianoalquil C1, C1 - 10 - alkyl carbonyl - C1 - 6 -, N - alkyl c1-3 alkyl - Aminocarbonyl - C1 - 6 -, N,N - (Aminocarbonyl c1-3 alkyl) - C1 - 6 - alkyl -, aryl alkyl - or aryl - C1 - 6 - 6 C1 alkyl aryl - in which the rest is replaced by one to three R7, which may be the same or different alkyl or heterociclil - C1 - C6 or heterociclil C1 - alkyl - 6 - in which the rest heterociclilo is replaced by one Three R7, which may be the same or different alkyl; and R16 is C1 - 6 or a Salt or n-oxide thereof.
机译:这也涉及制备式(1)化合物的方法,用于制备式(1)化合物的中间体,防治植物和包含式(1)化合物的组合物的方法。权利要求1:一种式(1)化合物式(1),其中R1和R2独立地是氢,c1-4烷基,卤代alquiloc1-4,卤代,氰基,羟基,烷氧基c1-4,Alquiltioc1-4,被一个或五个R6取代的芳基或芳基,可以是相同或不同的或杂芳基的杂芳基,或被1-5个相同或不同的R6取代; R3是氢,烷基C1-10卤代喹啉C1-4,2-4,10,卤代喹啉C2,2-4,4-,10,-4卤代喹啉C2,C3 C3环芳基环烷基-10,10-6-烷氧基烷基C1,C1-1-4 6-10-烷基-,芳基C1-10-10--萘甲醇C1 C1烷基-6-,N-烷基c1-3烷基-氨基羰基-C1-6-,N,N-(c1-3烷基)-氨基碳L-烷基C1-6-芳基烷基-或芳基-C1-6-6 C1烷基芳基-其中其余部分被1-3个相同或不同的R7取代,或杂基-C1-6-烷基或烷基杂环基-C1-6-,其中其余的杂环基被1至3个相同或不同的R 7取代; R4是被1至5个R8相同或不同的芳基或芳基或被1至4个R8相同或不同的杂芳基杂芳基; R5是羟基或可以在羟基中代谢的基团; R 6,R 7和R 8各自独立地为:卤素,C 1烷基,硝基,-10,-4烷氧基卤代alquilo C1,C2-10喹啉基C2 10,羟基,烷氧基,C 1-10,卤代烷氧基c 1-4烷氧基,C 1 -C 3 4烷基,环烷基-7环烷基C3 C3-7-7,环烷基c1-4烷基,烷氧基环烷基C1-C3-7-6-6-C1烷基羰基,Formilo(c1-4烷氧基羰基)-4-Alquiltio alquilcarboniloxi C1, C1-,10-,4-卤代alquiltio C1,C1 alquilsulfinil卤代磺胺C1--10-,4-,10-卤代alulfulfilil alquilsulfonil C1,C1-4-AM否,alquilamino C1-10-,di-alquilamino C1-C10,alquilcarbonilamino被1至3个相同或不同的R 13取代的C 1-10-芳基或芳基,或被相同或不同1至3个R 13取代的杂芳基杂芳基,芳基烷基-或芳基C 1-4烷基C 1-4 -芳基-其中其余的被1-3个R 13取代。可以等于或不同-杂芳基杂芳基烷基c1-4烷基-或-C1-4-其中其余为被一至三个R13取代的杂芳基,R13可以相同或不同,ariloxi-或ariloxi-取代为a-三个可以相同或不同的R13,杂芳基-被一个或一个杂芳基TR R13取代,可以相同或不同,ariltio-或ariltio-被一到三个R13取代,可以相同或不同,或杂芳基-或杂芳基-被一个或三个R13取代,R13可以相同或不同,并且每个R13独立地为烷基,氰基,硝基,卤代alquilo C1 -C1-6-6-烷氧基-或C1 6或其盐或正氧化物7.一种式(2)的化合物,其中R 1,R 2和R 4如权利要求1所定义,并且R 16是烷基C 1-6;权利要求8:另一组是式(1)的化合物,其中R 1,R 2和R 4如权利要求1所定义;或其盐或正氧化物。 R3是烷基烷基萘基C1-C2-10、10、10烷基喹啉基C2-C3-10,环烷基,环烷基C1 C3烷基-6-10-烷氧基烷基C1,C1-6-10-,10-烷氧基-芳基C1,C1 -10-烷基羰基-C1-6-N-烷基c1-3烷基-氨基羰基-C1-6-N,N-(氨基羰基c1-3烷基)-C1-6-烷基-芳基烷基-或芳基-C 1-6 -6 C 1烷基芳基-其中其余的被一至三个R 7取代,R 7可以是相同或不同的烷基或杂基-C 1 -C 6或杂基C 1-烷基-6-其中其余的杂基是被一个可以是相同或不同的烷基的三个R 7取代; R 16为C 1-6或其盐或正氧化物。

著录项

  • 公开/公告号AR069212A1

    专利类型

  • 公开/公告日2010-01-06

    原文格式PDF

  • 申请/专利权人 SYNGENTA LIMITED;

    申请/专利号AR2008P104858

  • 发明设计人

    申请日2008-11-06

  • 分类号C07D513/04;C07D241/28;A01N43/90;

  • 国家 AR

  • 入库时间 2022-08-21 18:47:33

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