首页> 外国专利> Procedure for the production of Polymer Strands of high tensile strength and low Permanent deformation of Polymers or copolymers, Strands of high tensile strength and low Permanent deformation and the use of such threads

Procedure for the production of Polymer Strands of high tensile strength and low Permanent deformation of Polymers or copolymers, Strands of high tensile strength and low Permanent deformation and the use of such threads

机译:聚合物或共聚物的高拉伸强度和低永久变形的聚合物股线的生产程序,高拉伸强度和低永久变形的聚合物股线的使用以及此类线的使用

摘要

Procedure for the production of Polymer Strands of high tensile strength Low Permanent deformation, characterized in that it comprises the following steps: a) preparing a mixture of: (i) a First Polymer or Copolymer of Ultra High Molecular Weight polyolefin, (ii) a Second C Opolu00edmero or polyolefin Polymer Clay nanocomposite and (iii) a nonpolar Solvent spinning,(b) feeding the resulting slurry through an Extruder at a temperature of at least 350f, causing the formation of a gel, The gel spinning c) obtained in a row with a ratio of length to diameter (L / d) of at least 15; (d) to cool The temperature by a thread below Of 35), and subsequently remove the non polar Solvent spinning,(f) to stretch the thread and thus obtained in order to achieve a tensile strength of at least 18 CN / dtex and a Lower Permanent deformation value of 0.07% per hour, where the first Polymer or Copolymer of Ultra High Molecular Weight polyolefin has a Molecular Weight Average Weight increased in 2000.000 g / mol and a polydispersity of at least 7 and the second polyolefin Copolymer or Polymer Clay nanocomposite is obtained through in situ polymerization of an olefin and an exfoliated clay layers, thus obtained the polyolefin having a Weight Average Molecular Weight d And at least 400 g / mol.
机译:生产高抗拉强度低永久变形聚合物链的方法,其特征在于它包括以下步骤:a)制备以下混合物:(i)超高分子量聚烯烃的第一聚合物或共聚物,(ii)a第二次C Opol u00edmero或聚烯烃Polymer Clay纳米复合材料,和(iii)非极性溶剂纺丝,(b)在至少350f的温度下将所得浆料通过挤出机进料,导致形成凝胶,获得凝胶纺丝c)长度与直径之比(L / d)至少为15的行; (d)通过低于35的线冷却温度,然后去除非极性的溶剂纺丝;(f)拉伸线,从而获得至少18 CN / dtex的拉伸强度;较低的永久变形值每小时0.07%,其中超高分子量聚烯烃的第一聚合物或共聚物的平均分子量增加2000.000 g / mol,且多分散度至少为7,第二聚烯烃共聚物或聚合物通过烯烃和剥离的粘土层的原位聚合获得粘土纳米复合材料,从而获得具有重均分子量d和至少400g / mol的聚烯烃。

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