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PROCESS FOR MAKING A CARBON NANOTUBES/ULTRA-HIGH MOLAR MASS POLYETHYLENE COMPOSITE FIBRE

机译:制备碳纳米管/超高分子量聚乙烯复合纤维的方法

摘要

The invention relates to a process for making a carbon nanotubes / ultra-high molar mass polyethylene (CNTs/UHPE) composite fibre comprising the steps of a) pre-treating CNTs with an acidic aqueous solution; b) making a composition containing pre-treated CNTs dispersed in a solution of UHPE in a spin solvent; and c) spinning the composition obtained into fibres; wherein step b) comprises making a dispersion of pre-treated CNTs in an alcohol, and mixing this dispersion with a mixture of UHPE and spin solvent. With this process CNTs/UHPE composite fibres showing improved tensile properties are obtained at relatively low CNTs content. A further advantage is that no or hardly any additional components, like dispersion aids, need to be added to make a stable dispersion of CNTs in the spin composition. The invention also relates to a CNTs/UHPE composite fibre obtainable by the process according to the invention, and to semi-finished or end-use articles containing said composite fibre.
机译:本发明涉及制备碳纳米管/超高摩尔质量聚乙烯(CNTs / UHPE)复合纤维的方法,该方法包括以下步骤:a)用酸性水溶液预处理CNT; b)制备包含分散在UHPE在旋转溶剂中的溶液中的预处理的CNT的组合物; c)将得到的组合物纺成纤维;其中步骤b)包括制备预处理的CNT在醇中的分散体,并将该分散体与UHPE和旋转溶剂的混合物混合。通过该方法,以相对较低的CNT含量获得了显示出改善的拉伸性能的CNT / UHPE复合纤维。另一个优点是不需要或几乎不需要添加任何其他组分,例如分散助剂,以使CNT在纺丝组合物中稳定分散。本发明还涉及可通过根据本发明的方法获得的CNT / UHPE复合纤维,并且涉及包含所述复合纤维的半成品或最终用途的制品。

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