首页> 外国专利> IMPROVED MONOVINYLIDENE AROMATIC POLYMERS COMPRISING SULFANYLSILANE FUNCTIONALIZED ELASTOMERIC POLYMERS

IMPROVED MONOVINYLIDENE AROMATIC POLYMERS COMPRISING SULFANYLSILANE FUNCTIONALIZED ELASTOMERIC POLYMERS

机译:包含硫磺基功能化弹性聚合物的单乙烯基芳烃的改进

摘要

The present invention is a rubber modified monovinylidene aromatic polymer composition where the rubber is a sulfanylsilane chain end modified elastomeric polymer. In the present invention the functionalized rubber provides sufficient grafting levels in standard graft polymerization process technologies to prepare desired rubber particle size distributions and morphologies. Across a range of rubber modified monovinylidene aromatic polymers, it has been found that the use of the modified elastomeric polymers according to the present invention can improve the combinations of resin properties, particularly clarity, surface and physical properties, including both rubber modified monovinylidene aromatic homopolymers (e.g., high impact polystyrene and copolymers (e.g., ABS). The functionalized rubbers have sulfanyl functional groups that provide an optimized reactive grafting site. This ensures that under graft polymerization conditions a monovinylidene aromatic polymer block is formed grafted to the butadiene polymer block. This is particularly desirable to enable the use of polybutadiene homopolymer rubbers which are more cost effectively used in rubber-modified monovinylidene aromatic polymers.
机译:本发明是橡胶改性的单亚乙烯基芳族聚合物组合物,其中橡胶是硫烷基硅烷链端改性的弹性体聚合物。在本发明中,官能化橡胶在标准接枝聚合工艺技术中提供了足够的接枝水平,以制备所需的橡胶粒度分布和形态。在一系列橡胶改性的单亚乙烯基芳族聚合物中,已经发现,根据本发明的改性的弹性体聚合物的使用可以改善树脂性能,特别是透明度,表面和物理性能的组合,包括橡胶改性的单亚乙烯基芳族均聚物。 (例如,高抗冲聚苯乙烯和共聚物(例如,ABS)。官能化的橡胶具有硫烷基官能团,可提供最佳的反应性接枝位点。这可确保在接枝聚合条件下,将单亚乙烯基芳族聚合物嵌段接枝到丁二烯聚合物嵌段上。为了能够使用在橡胶改性的单亚乙烯基芳族聚合物中更具成本效益的聚丁二烯均聚物橡胶,这是特别希望的。

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