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Hydrocracking catalyst which comprises EDUCATED IN SITU Y-faujasite and hydrocracking process

机译:包括原位Y-八面沸石和加氢裂化工艺的加氢裂化催化剂

摘要

1. The hydrocracking process and recovery of hydrocarbons, which comprises reacting a petroleum fraction with a catalyst and hydrogen at hydrocracking conditions required, wherein the catalyst consists of a combination of metals that catalyze the hydrogenation and zeolite layer is crystallized onto the surface of a porous alumina-matrix, where the matrix layer is a zeolite with such a structure to provide macropores, which is formed on the walls of the zeolite layer, wherein said process also includes the recovery of oil fractions boiling at temperatures below about 200 ° C.;2. Process according to claim 1, wherein the metal which catalyzes the hydrogenation is selected from the group consisting of metals of Groups VA, VIA, and VIIIA of the Mendeleev periodic system of elements.;3. The process of claim 1 wherein the oil fraction - fraction is hydrotreated oil.;4. Process according to claim 1, where the matrix layer is incorporated with the zeolite with a binder to form a bound zeolite which zeolite bound shaped extrusion.;5. The process of claim 1, wherein the zeolite - Y is a zeolite.;6. The process of claim 1 wherein the porous matrix of alumina-shaped, eg by extrusion, and the zeolite formed in-situ in the matrix.;7. The process of claim 1 wherein the matrix layer with a porosity zeolite obtained by mercury porosimetry, of at least 0.07 cm3/ G for a pore diameter 600-20000 Å.;8. A hydrocracking catalyst which comprises a matrix formed by metals that catalyze the hydrogenation and zeolite layer is crystallized onto the surface of a porous alumina-matrix, where the matrix layer is a zeolite with a structure to provide macropores walls on which the zeolite layer is formed.;9. The catalyst of claim 8, wherein the zeolite formed in-situ in the alumina-matrix.;10. The catalyst of claim 8, wherein the catalyst is in the form of 1/16 to 1/8 inch extrudate.
机译:1.加氢裂化过程和烃的回收,其包括在所需的加氢裂化条件下使石油馏分与催化剂和氢气反应,其中催化剂由催化氢化的金属的组合组成,并且沸石层结晶到多孔表面上。氧化铝基质,其中基质层是具有提供大孔的结构的沸石,其形成在沸石层的壁上,其中所述方法还包括回收在低于约200℃的温度下沸腾的油馏分; 2。 2.根据权利要求1的方法,其中催化氢化的金属选自门捷列夫元素周期系统的VA,VIA和VIIIA族金属; 3。权利要求1的方法,其中油馏分-馏分是加氢处理的油。4。 2.根据权利要求1所述的方法,其中,将所述基质层与具有粘结剂的沸石结合以形成粘结的沸石,所述沸石将粘结的挤出成型。 2.根据权利要求1所述的方法,其中,所述沸石-Y是沸石。 8.根据权利要求1所述的方法,其中所述氧化铝形状的多孔基质例如通过挤出形成,并且所述沸石在所述基质中原位形成。 7,根据权利要求1的方法,其中具有通过水银孔隙率法测得的孔隙度为至少0.07cm 3 / G的沸石的基质层,其孔径为600-20000。包含由催化氢化的金属形成的基质的加氢裂化催化剂和沸石层在多孔氧化铝基体的表面上结晶,其中该基质层是具有结构的沸石,该结构具有提供在其上形成沸石层的大孔壁的结构。 。; 9。 9.根据权利要求8所述的催化剂,其中,所述沸石在所述氧化铝基质中原位形成。 9.根据权利要求8所述的催化剂,其中,所述催化剂为1/16至1/8英寸挤出物的形式。

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