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METHOD AND APPARATUS FOR THE PRODUCTION OF NATURAL GAS SUBSTITUTES

机译:用于生产天然气代用品的方法和装置

摘要

1. A method of producing substitute natural gas (ZPG) of fresh raw syngas (11), including at least the reaction stages fresh synthesis gas section (10) methanation comprising at least a first adiabatic reactor (101) and other adiabatic reactor (s) (102-104) connected in parallel, so that each of them receives a gas stream withdrawn from the preceding reactor methanation section, and is carried out by recycling at least a portion (22) of the reaction gas as a raw gas at at least one of reactors, wherein said fresh syngas feedstock (11) is fed in parallel to said reactors (101-104). ! 2. The method of claim 1, wherein said fresh syngas feedstock (11) is divided into a series of fresh gas streams (12, 14, 15, 16), each of which is fed into one of the reactors (101-104). ! 3. The method of claim 2, wherein each of said fresh gas streams (12, 14, 15, 16) is 15-35 mol.% Of the total flow (11) of the gas feed. ! 4. The method of claim 1, wherein the step of gas recirculation is carried out by selection portion (22) of the reaction gas flow (20) from the first reactor (101) and using said portion (22) of the gas as a recycle gas for the dilution flow (12) of fresh gas entering the first reactor (101) to obtain a flow (18) of the diluted gas at the inlet of the first reactor. ! 5. The method of claim 4, wherein the portion (22) of the reaction gas flow fed to the inlet of the first reactor (101) on the recirculation loop (40) comprising a compressor (23) to the recycle gas stream (22) and the heater (17 ) for heating said diluted gas stream before entering the first reactor (101). ! 6. The method of claim 4,
机译:1.一种生产新鲜的粗合成气(11)的替代天然气(ZPG)的方法,其至少包括至少包括第一绝热反应器(101)和其他绝热反应器的甲烷化反应的新鲜合成气部分(10)的甲烷化。 )(102-104)并联连接,以使它们各自接收从前一反应器甲烷化段抽出的气流,并通过将至少一部分反应气体(22)作为原料气在90°C循环进行。至少一个反应器,其中将所述新鲜合成气原料(11)与所述反应器(101-104)平行地进料。 ! 2.根据权利要求1所述的方法,其中,将所述新鲜的合成气原料(11)分成一系列新鲜的气流(12、14、15、16),将它们中的每一个进料到一个反应器(101-104)中。 。 ! 3.根据权利要求2所述的方法,其特征在于,每个所述新鲜气流(12、14、15、16)为气体进料的总流量(11)的15-35摩尔%。 ! 4.根据权利要求1所述的方法,其中,通过来自所述第一反应器(101)的反应气流(20)的选择部分(22)并使用所述气体的所述部分(22)来进行气体再循环的步骤。为进入第一反应器(101)的新鲜气体的稀释流(12)循环气体,以在第一反应器的入口获得稀释气体的流(18)。 ! 5.根据权利要求4所述的方法,其中,在包括对所述再循环气流(22)的压缩机(23)的再循环回路(40)上,供给到所述第一反应器(101)的入口的所述反应气流的部分(22)。 )和加热器(17),用于在进入第一反应器(101)之前加热所述稀释的气流。 ! 6.根据权利要求4所述的方法,

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