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New 2,6-pyrazine bridged transition metal carbene complex useful as a catalyst for oxidation of hydrocarbons

机译:新型2,6-吡嗪桥联的过渡金属卡宾配合物可用作烃氧化的催化剂

摘要

2,6-Pyrazine bridged transition metal carbene complex (I), is new. 2,6-Pyrazine bridged transition metal carbene complex of formula (I), is new. M : transition metal, preferably a transition metal of the VIII subgroup of the periodic system of elements; Hal : halide comprising Cl, Br or I; L : mono or bidentate ligand; R1 : phenyl or 7-12C-arylalkyl (both optionally substituted) or 1-12C-alkyl; either R2, R3 : H; or R2R3 : optionally substituted phenyl ring; and n : 1-3. Independent claims are included for: (1) pyrazine compound of formula (II); and (2) the preparation of (I). [Image] [Image].
机译:2,6-吡嗪桥联的过渡金属卡宾配合物(I)是新的。式(I)的2,6-吡嗪桥联的过渡金属卡宾配合物是新的。 M:过渡金属,优选元素周期系统的VIII亚族的过渡金属; Hal:包含Cl,Br或I的卤化物; L:单或双齿配体; R1:苯基或7-12C-芳基烷基(均任选被取代)或1-12C-烷基; R2,R3:H;或R 2 R 3:任选取代的苯环;或n:1-3。包括以下独立权利要求:(1)式(II)的吡嗪化合物; (2)制备(I)。 [图片] [图片]。

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