首页> 外国专利> Electrically or magnetically stimulatable material useful in medicine technology, which changes its mechanical properties during applying electric current and electric/magnetic field within very short time, comprises first and second layer

Electrically or magnetically stimulatable material useful in medicine technology, which changes its mechanical properties during applying electric current and electric/magnetic field within very short time, comprises first and second layer

机译:可用于医学技术的电刺激或磁刺激材料,包括第一层和第二层,可在极短时间内施加电流和电场/磁场的过程中改变其机械性能

摘要

The electrically or magnetically stimulatable material, which changes its mechanical properties during applying an electric current and an electric/magnetic field within very short time, where a multi-layered material is produced on basis of polyetherurethane by extrusion/injection molding, comprises a first layer made of polyetherurethane on the basis of polyether alcohol of the hydroxyl functionality of 1.95-2.95 and molar mass of 1000-6000 with organic nanoparticles embedded and/or integrated in polymer chain, short chain diols, optionally further additives and di-and/or polyisocyanates. The electrically or magnetically stimulatable material, which changes its mechanical properties during applying an electric current and an electric or magnetic field within very short time, where a multi-layered material is produced on the basis of polyetherurethane by extrusion or injection molding, comprises a first layer made of polyetherurethane on the basis of polyether alcohol of the hydroxyl functionality of 1.95-2.95 and the molar mass of 1000-6000 with organic nanoparticles embedded and/or integrated in the polymer chain, short chain diols, optionally further additives and di-and/or polyisocyanates, and a second layer made of polyetherurethane on the basis of polyether alcohol of the hydroxyl functionality of 1.95-2.95 and the molar mass of 1000-5000 with inorganic nanoparticles embedded and/or integrated in the polymer chain, short chain diols, optionally further additives and di-and/or polyisocyanates. The layers undetachably join with one another during the processes on the basis of physical or chemical interactions, so that the composite material receives an alignment of the inorganic particles during applying a voltage or electric or magnetic field, where the property of the material suddenly changes and the outer shell and/or outer lying layer effectively prevents an interaction with the environment. The first layer is structured on the basis of nanoscale organic dispersions in polyether alcohols, which are produced by depolymerization of polyurethane-cold-form soft foam materials using a glycol mixture in presence of polyamine with secondary and primary aminogroups and subsequent stabilization with polypropylene glycol and optionally further glycol, glycols as chain extenders and diisocyanate and/or the first layer is structured on the basis of nanoscale organic dispersions in polyether alcohols, which are produced by depolymerization of urea-formaldehyde condensates using glycol and water, glycols as chain extenders and diisocyanate. The second layer is structured on the basis of polyether alcohols with nanoscale metal oxides, metal oxide hydrates and/or metal hydroxides of iron metals dispersed in it, glycols as chain extenders and diisocyanate, the second layer is structured on the basis of polyether alcohols with nanoscale complex mixed oxides or mixed hydroxides of iron metals dispersed in it and silicon, germanium, rare earth metals as carrier, glycols as chain extenders and diisocyanate, the second layer is structured on the basis of polyether alcohols with nanoscale complex iron mixed oxides dispersed in it, glycols as chain extenders and diisocyanate and/or the second layer is structured on the basis of polyether alcohols with nanoscale complex mixture of manganese-, cobalt- or nickel oxides dispersed in it, glycols as chain extenders and diisocyanate. Independent claims are included for: (1) a method for producing an electrically or magnetically stimulatable material; (2) a method for generating mechanical property changes of polymeric composite material; and (3) a molded body for reaction at a permanent magnetic field.
机译:可电刺激或可磁刺激的材料包括第一层,该材料在非常短的时间内施加电流和电场/磁场期间会改变其机械性能,其中在聚醚氨酯的基础上通过挤出/注射成型生产出多层材料由基于羟基官能度为1.95-2.95且摩尔质量为1000-6000的聚醚醇的聚醚氨基甲酸酯制成,其中有机纳米颗粒嵌入和/或集成在聚合物链中,短链二醇,可选的其他添加剂和二和/或多异氰酸酯。可以在短时间内施加电流和电场或磁场的过程中改变其机械性能的电刺激或磁刺激材料,其中基于聚醚氨酯通过挤出或注塑成型生产多层材料,该材料包括第一由聚醚氨基甲酸酯制成的层,其基于羟基官能度为1.95-2.95且摩尔质量为1000-6000的聚醚醇,并嵌入和/或集成在聚合物链中的有机纳米粒子,短链二醇,可选的其他添加剂和二和和/或多异氰酸酯,以及第二层,其基于羟基官能度为1.95-2.95,摩尔质量为1000-5000的聚醚醇,其中的无机纳米颗粒嵌入和/或集成在聚合物链中,短链二醇,任选地,其他添加剂和二和/或多异氰酸酯。在物理或化学相互作用的基础上,各层在处理过程中彼此不可分离地结合在一起,因此复合材料在施加电压,电场或磁场的过程中会接受无机颗粒的排列,其中材料的性质突然发生变化,外壳和/或外层有效地防止了与环境的相互作用。第一层是基于聚醚醇中的纳米级有机分散体构建的,该分散体是通过在聚胺与仲氨基和伯氨基的存在下,使用乙二醇混合物对聚氨酯冷形式的软泡沫材料进行解聚,然后用聚丙二醇和丙二醇稳定而制得的。任选地,另外的二醇,作为增链剂的二醇和二异氰酸酯和/或第一层是基于聚醚醇中的纳米级有机分散体构造的,所述有机分散体是通过使用二醇和水将脲-甲醛缩合物解聚而制得的,二醇为增链剂和二异氰酸酯。第二层基于聚醚醇与分散在其中的纳米级金属氧化物,金属氧化物水合物和/或铁金属的金属氢氧化物,作为增链剂的二醇和二异氰酸酯构成,第二层基于聚醚醇与分散在其中的铁金属的纳米级复杂混合氧化物或混合氢氧化物,以及硅,锗,稀土金属作为载体,乙二醇作为扩链剂和二异氰酸酯,第二层是基于聚醚醇构建的,纳米级复杂的铁混合氧化物分散在其中在此,作为扩链剂的二醇和二异氰酸酯和/或第二层是基于聚醚醇和分散在其中的锰,钴或镍的氧化物的纳米级复杂混合物,作为扩链剂的二醇和二异氰酸酯构成的。包括以下独立权利要求:(1)一种生产可电或磁刺激材料的方法; (2)产生聚合物复合材料的机械性能变化的方法; (3)在永久磁场下反应的成型体。

著录项

  • 公开/公告号DE102008044388A1

    专利类型

  • 公开/公告日2010-06-10

    原文格式PDF

  • 申请/专利权人 REDTEL HOLGER;

    申请/专利号DE20081044388

  • 发明设计人 REDTEL HOLGER;

    申请日2008-12-05

  • 分类号B32B27/40;C08J3/20;C08J5/00;C08J5/12;C08K7/00;H01F1/44;

  • 国家 DE

  • 入库时间 2022-08-21 18:28:45

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