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Production method of alkyl benzene hydro Pell oxide

机译:烷基苯加氢佩尔氧化物的生产方法

摘要

In the production method of alkyl benzene hydro Pell oxide, (i) sec-buchiru benzene, 10 mass of the (ii) all the supply raw materials % the cumene of a larger quantity and 20 mass of the (iii) all the supply raw materials % to iso of the quantity - the supply raw materials which include at least the kind of butyl benzene and tert-buchiru benzene are made to contact with the oxygen content gas under existing of the catalyst which includes the annular imido below-mentioned general formula (i). The contact is done under the condition for converting sec-buchiru benzene and cumene to those related hydro Pell oxides.[In formula, R husband of1 and R2 hidorokarubiru basis and substitution hidorokarubiru basis or basis SO3 H and NH2 which possess 1 - 20 carbon atoms in independence, OH, and to be chosen from NO,2 or atom H, F, Cl, Br, and I however, R1 and R2 to designate that it can connect mutually with covalent bond as a condition, Q husband of1 and Q2 in independence C, to be chosen from CH, N and CR3, as for husband of X and Z in independence C, S and CH2It is chosen from the element of 4 families of N, P and the periodic table, Y is O or OH, k is 0, 1 or 2, l is 0, 1 or 2, m is 1 - 3, at the same time R3 may be either of those which the list are done concerning R1] Selective figure Figure 13
机译:在烷基苯加氢佩尔氧化物的制造方法中,(i)仲丁基苯中,(ii)全部供给原料中的10质量%为异丙苯,较大量的异丙苯和(iii)全部供给原料中的20质量%。相对于量的等量的%-使包含环状亚氨基的下述通式的催化剂的存在下,使至少包含丁基苯和叔丁苯的种类的供给原料与含氧气体接触(一世)。接触是在将仲-布奇鲁苯和枯烯转化为相关的氢化佩尔氧化物的条件下进行的。取代hidorokarubiru基或基SO 3 H和NH 2,其中具有1-20个独立的碳原子,OH,并选自NO, 2 或原子H,F,Cl,Br和I,但是,R 1 和R 2 表示它可以与共价键相互连接为条件Q独立C中的 1 和Q 2 的丈夫,从CH,N和CR 3 中选择,如X和Z的丈夫独立性C,S和CH 2 它选自N,P和周期表的4个族的元素,Y为O或OH,k为0、1或2,l为0, 1或2,m为1-3,同时R 3 可能是与R 1 ] <选择图>列表有关的任何一个

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