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In order production mannered null optical purity 95 or more

机译:为了生产出合格的光学纯度达到95%以上

摘要

PROBLEM TO BE SOLVED: To obtain a molded article which is prepared by subjecting a sheet comprising a polylactic acid and a neucleating agent to heat treatment and which is excellent in heat resistance and impact resistance.;SOLUTION: The molded article consists of a crystalline polylactic acid resin (A) having an optical purity of 95% or higher, an aromatic/aliphatic copolyester or aliphatic polyester (B) having a glass transition temperature of 0°C or lower, and a talc (C) having a mean particle diameter of 1-8 μm. The ratio of the resin (A) to the polyester (B) is (97:3) to (80:20) by mass, and the talc (C) accounts for 1-30 mass% of the whole composition. The molded article has a crystallization index, which is a difference in absolute values between the heat of crystal fusion ΔHm measured by a differential scanning calorimeter at a temperature-rise rate of 20°C/min and the heat of crystallization for temperature-rise ΔHc, satisfying the relation of formula: (|ΔHm|-|ΔHc|)≥25 J/g, a rate of crystallization at 130°C of 0.010 min-1 or higher, and a falling ball impact strength, in terms of the height of a falling ball, of 20 cm or higher at a thickness of 500 μm.;COPYRIGHT: (C)2004,JPO&NCIPI
机译:解决的问题:要获得模制品,该模制品是通过对包含聚乳酸和成核剂的片材进行热处理而制得的,并且其耐热性和耐冲击性优异。解决方案:模制品由结晶聚乳酸组成光学纯度为95%或更高的酸性树脂(A),玻璃化转变温度为0°C或更低的芳族/脂族共聚酯或脂族聚酯(B)和滑石粉(C)的平均粒径为1-8微米树脂(A)与聚酯(B)的质量比为(97:3)〜(80:20),滑石(C)占组合物整体的1〜30质量%。模制品具有结晶指数,该结晶指数是通过差示扫描量热仪在20℃/ min的升温速率下测得的晶体熔化热ΔHm与温度-下的结晶热之间的绝对值之差。上升ΔHc,满足下式的关系:(|ΔHm|-|ΔHc|)≥ 25 J / g,在130℃下的结晶速度为0.010min -1 或更高,并且落球冲击强度(落球高度)在20厘米或更高且厚度为500μm时;版权:(C)2004,JPO&NCIPI

著录项

  • 公开/公告号JP4808367B2

    专利类型

  • 公开/公告日2011-11-02

    原文格式PDF

  • 申请/专利权人 ユニチカ株式会社;

    申请/专利号JP20030059257

  • 发明设计人 日置 正信;西村 弘;

    申请日2003-03-06

  • 分类号C08L67/04;B29C51/10;C08K3/34;C08L101/16;B29K67/00;

  • 国家 JP

  • 入库时间 2022-08-21 18:20:05

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