首页> 外国专利> Catalyst For Direct Conversion Of Esters Of Lactic Acid To Lactide And The Method For Producing Lactide Using The Same

Catalyst For Direct Conversion Of Esters Of Lactic Acid To Lactide And The Method For Producing Lactide Using The Same

机译:乳酸酯直接转化为丙交酯的催化剂及其制备丙交酯的方法

摘要

The present disclosure discloses a catalyst for directly producing a lactide which is a cyclic ester used as a monomer for polylactides, and a method for directly producing a lactide using the catalyst, the method including the transesterification reaction between two molecules of an ester of lactic acid or a mixture containing the ester of lactic acid with a small amount of lactic acid and oligomer of lactic acid under an inert environment in the presence of a titanium-based catalyst or a catalyst mixture containing the titanium-based catalyst so as to produce lactide while simultaneously removing an alcohol (ROH) generated as a by-product. As compared to a conventional commercialized process, since the method for producing a lactide in accordance with the present disclosure is a novel process capable of directly producing the lactide from the ester of lactic acid, energy consumption is low and the lactide can be produced through a simple process showing a high yield while maintaining optical property (D-form or L-form optical isomer).
机译:本公开公开了一种用于直接生产作为聚乳酸的单体的环状酯的丙交酯的催化剂,以及使用该催化剂直接生产丙交酯的方法,该方法包括乳酸的两个分子之间的酯交换反应。或在惰性环境下,在钛基催化剂或含有钛基催化剂的催化剂混合物的存在下,在惰性环境下将含有乳酸的酯与少量乳酸和乳酸的低聚物的混合物制得丙交酯,同时去除副产物酒精(ROH)。与常规的商业化方法相比,由于根据本公开的生产丙交酯的方法是能够直接从乳酸的酯直接生产丙交酯的新方法,因此能量消耗低并且可以通过以下方法生产丙交酯。简单的方法,显示出高收率,同时又保持了光学特性(D型或L型光学异构体)。

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