Use of derivatives of merocianina, monomeric and polymeric compounds, cosmetic preparation, as well as dispersion of UV absorption

摘要

Use of derivatives of merocianina, monomeric and polymeric compounds, cosmetic preparation, as well as dispersion of UV absorption.The present invention relates to the use of derivatives of merou00e7ianina formula where q is hydrogen; C ~ 1 ~ C ~ 22 ~ aiquiia; Oh; - or ~ 7 ~, - NR ~ 7 ~ R ~ 8 ~; or - n = R ~ 9 ~ R ~ 1 ~ is; hydrogen; C ~ 1 ~ C ~ 22 ~ aiquiia; - or ~ 7 ~,- Mr. ~ 7 ~, - NR ~ 7 ~ R ~ 8 ~; C ~ 1 ~ C ~ 22 ~ aiquiia; C ~ 2 ~ - C ~ 12 ~ alquenila; C ~ 2 ~ - C ~ 12 ~ alquinila; C ~ 3 ~ C ~ 12 ~ cicloalquila; C ~ 3 ~ C ~ 12 ~ cicloalquenila; C ~ 7 ~ C ~ 12 ~ aralquila; C ~ 1 ~ C ~ 12 ~ heteroalquila, C ~ 2 ~ - C ~ 11 ~ heteroaralquila; C ~ 6 ~ C ~ 10 ~ ariia; or C ~ 1 ~ C ~ 9 ~ heteroariu00eda; R. ~ 4 ~ is cyan colored; ~ 7 ~,Coor ~ 7 ~; conr ~ 7 ~ R ~ 8 ~; only ~ 2 ~ (C ~ 6 ~ C ~ 12 ~) arila; C ~ 2 ~ - C ~ 12 ~ Alq - 1 - enila; C ~ 3 ~ C ~ 12 ~ cicloalq - 1 - enila; C ~ 2 the ~ C ~ 12 ~ AIQ - 1 - inila; C ~ 2 ~ - C ~ 12 ~ heteroalquila; C ~ 3 ~ C ~ 5 ~ heterocicloalquila; C ~ 6 ~ C ~ 10 ~ ariia; or C ~ 1 ~ C ~ 9 ~ heteroarila; R ~ 5 ~ is color ~ 7 ~; - coor ~ 7 ~ ~ ~ 7; or; - Mr ~ 7 ~, - NHR ~ 7 ~,- NR ~ 7 ~ R ~ 8 ~; C ~ 1 ~ C ~ 22 ~ aiquiia; C ~ 2 ~ - C ~ 12 ~ alquenila; C ~ 2 ~ - C ~ 12 ~ alquinila; C ~ 3 ~ C ~ 12 ~ cicloalquila; C ~ 3 ~ C ~ 12 ~ cicloalquenila; C ~ 7 ~ C ~ 12 ~ aralquila; C ~ 1 ~ C ~ 12 ~ alquilfenila; C ~ 1 ~ C ~ 12 ~ alcu00f3xi - C ~ 6 ~ C ~ 10 ~ ariia; C ~ 1 ~ C ~ 12 ~ heteroalquila; C ~ 2 ~ - C ~ 11 ~ 1heteroaralquila; C ~ 3 ~ C ~ 12 ~ cicloet Eroalquila; C ~ 6 ~ C ~ 10 ~ ariia; C ~ 1 ~ C ~ 12 ~ alcu00f3xi - C ~ 6 ~ C ~ 10 ~ ariia; or C ~ 1 ~ C ~ 9 ~ heteroarila; R ~ 6 ~Is hydrogen; C ~ 1 - C ~ 22 ~ aiquiia; C ~ 1 ~ C ~ 22 ~ alcu00f3xi; or color ~ 7 ~ R ~ 7 ~ and ~ R ~ 8 independently of one another.Are hydrogen; C ~ 1 ~ C ~ 22 ~ aiquiia; C ~ 2 ~ - C ~ 12 ~ alquenila; C ~ 2 ~ - C ~ 12 ~ alquinila; C ~ 3 ~ C ~ 12 ~ cicloalquila; C ~ 3 ~ C ~ 12 ~ cicloalquenila; - (CH ~ 2 ~.) tcooh; C ~ 7 ~ C ~ 12 ~ aralquila; C ~ 1 ~ C ~ 12 ~ heteroalquila; C ~ 2 ~ - C ~ 11 ~ heteroaralquila; C ~ 6 ~ C ~ 10 ~ ariia; C ~ 1 ~ C ~ 9 ~ heteroarila; Si - R ~ 10 ~ R ~ 11 ~ R ~ 12 ~; Si (or ~ 10 ~) (or ~ 11 ~) (or ~ 12 ~); or a radical X - IBS; t, u and V, independently of each other.There are a number of 1 to R ~ 9 ~ is a radical (C ~ 1 ~ C ~ 6 ~) alquilideno; R ~ 10 ~ R ~ 11 ~ R ~ 12 ~ independently of one another, are C ~ 1 ~ C ~ 22 ~ aiquiia; X is a ligand; SIL. It is a radical silane or polysiloxane, oligossiloxano; R ~ 1 ~ R ~ 2 ~ R ~ 1 ~ and Q, R ~ 1 ~ R ~ 6 ~ R ~ 1 ~ and T, R ~ 2 ~ R ~ 3 ~ R ~ 2 ~. And R ~ 4 ~ R ~ 2 ~ R ~ 6 ~ R ~ 2 ~ e Q, R ~ 4 ~ R ~ 6 ~ R ~ 4 ~ and T, R ~ 6 ~ and Q, t and Q, each one independently.They are connected together, so that 1, 2, 3, or 4 rings carbocu00edclicos heterocyclic or with N, and / or s are formed, where each, independently of one another, can be condensed with an aromatic ring or heteroaromu00e1tico, and / or more heterocyclic rings with N, and / or s.And every atom of N in a ring Hetrocyclic with n can be replaced by C ~ 1 ~ C ~ 22 ~ aiquila; n is a number from 1 to 4; at least one of the radicals R ~ 1 ~ R ~ 6 ~ or q is different from hydrogen; n = 1 t is color ~ 5 ~, - CN; C ~ 6 ~ C ~ 10 ~ arila; - NHR ~ 5 ~; or so ~ 2 ~ - (C ~ 6 ~ C ~ 12 ~) arila; R ~ 2 ~. And R ~ 3 ~, independently of each other.They are C ~ 1 ~ C ~ 22 ~ alkyl; hydroxy - C ~ 1 ~ C ~ 22 ~ alkyl; C ~ 2 ~ - C ~ 12 ~ alquenila; C ~ 2 ~ - C ~ 12 ~ alquinila; C ~ 3 ~ C ~ 12 ~ cicloalquila,C ~ 3 ~ C ~ 12 ~ cicloalquenila; C ~ 7 ~ C ~ 12 ~ aralquila; C ~ 1 ~ C ~ 12 ~ heteroalquila; C ~ 3 ~ C ~ 12 ~ cicloetero - alkyl; C ~ 6 ~ C ~ 10 ~ arila; C ~ 1 ~ C ~. 9 ~ heteroarila; or a radical of the formula P is a nu00famerode 5A 100 q is a number from 1 to 5; y is a number from 0 to 4; if n = 2 ~ R ~ 2 and R ~ 3 ~ are, each one.C ~ 1 ~ C ~ 5 ~ alkylene; and at the same time t is defined as n = 1; and t is a divalent radical of formula - NR ~ 7 ~ - V - NR ~ 7 ~ -, in which V is phenylene, or C ~ 1 ~ C ~ 5 ~ alkylene; R ~. 7 ~ is hydrogen; or 01 - c5alquila; and R2 and R3 are ultaneamente are defined as for n = 1; if n = 3 a of R ~ 2 ~ r ~ 3 ~ or T is a trivalent radical; n = 4, R ~ 2 ~,R ~ 3 ~ or T is a quadrivalent radical; for the protection of the hair and skin of human beings against the harmful effects of UV radiation.