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Primary PVC plasticizers derived from vegetable oils, process for obtaining primary PVC plasticizers derived from vegetable oils and plasticized PVC composition

机译:衍生自植物油的初级PVC增塑剂,获得衍生自植物油的初级PVC增塑剂和增塑PVC组合物的方法

摘要

The present descriptive report refers to a patent of invention of primary PVC plasticizers composed of epoxidized ethyl and/or isoamyl esters of vegetable oil fatty acids and to the compounds of PVC plasticized with epoxidized bioesters, belonging to the technical field of polymer additives, developed from renewable sources such as vegetable oils and sugar cane, to reduce the cost and improve the properties of PVC compounds. The epoxidized bioesters are suitable to be added to at least one PVC resin and are obtained from a transesterification reaction of at least one type of vegetable oil with ethanol or isoamylic alcohol and subsequent epoxidation, presenting oxirane index equal to or less than 8. These primary plasticizers provide improvements to the properties of the compounded PVC not foreseen in the state of the art, such as better physical properties at low temperatures, greater flexibility of the final compound, higher mixing efficiency of the resin, improved resistance to aliphatic solvents extraction and improved resistance to UV degradation.
机译:本描述性报告涉及由植物油脂肪酸的环氧化的乙基和/或异戊酯组成的主要PVC增塑剂的发明专利,以及由环氧化的生物酯增塑的PVC化合物,属于聚合物添加剂技术领域,由可再生资源,例如植物油和甘蔗,以降低成本并改善PVC化合物的性能。环氧化的生物酯适合添加到至少一种PVC树脂中,并且是由至少一种类型的植物油与乙醇或异丁醇的酯交换反应得到的,然后环氧化,环氧乙烷指数等于或小于8。增塑剂可改善现有技术中未预见的复合PVC的性能,例如在低温下具有更好的物理性能,最终化合物具有更大的柔韧性,树脂的混合效率更高,对脂族溶剂萃取的抵抗力得到改善以及抗紫外线降解。

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