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POLYMER TYPE PHOSPHOR-CONTAINING FLAME RETARDANT, PREPARATION METHOD AND APPLICATION THEREOF

机译:聚合物型含磷阻燃剂,制备方法及其应用

摘要

Disclosed are a polymer type phosphor-containing flame retardant, preparation method and application thereof, which belong to the field of chemical materials. The polymer type phosphor-containing flame retardant PNX is a compound shown in formula (1), wherein n is an integer of 5~8 and the molecular weight of the flame retardant is between 900 and 1400. The method for preparing the flame retardant PNX is as follows: reacting phosphorus oxychloride with ethylene glycol in a nitrogen environment through a chemical reaction shown in the reaction formula (1) to obtain a compound (2), then reacting the compound (2) with anhydrous ethanol through a chemical reaction shown in reaction formula (2) under the action of a catalyst aluminum chloride to produce the flame retardant PNX. The flame retardant PNX belongs to a halogen-free, phosphorous type flame retardant. It coincides with the national concept of green-environmentally-friendly development. The content of phosphor is as high as 18%~20%, and the flame retardant properties are excellent.
机译:本发明公开了一种聚合物型含磷阻燃剂及其制备方法和应用,属于化学材料领域。聚合物型含荧光体的阻燃剂PNX为式(1)所示的化合物,其中n为5〜8的整数,且阻燃剂的分子量为900〜1400。制备阻燃剂PNX的方法如下:在氮环境下,通过反应式(1)所示的化学反应使三氯氧化磷与乙二醇反应,得到化合物(2),然后通过图3所示的化学反应,使化合物(2)与无水乙醇反应。反应式(2)在催化剂氯化铝的作用下制得阻燃剂PNX。阻燃剂PNX属于无卤磷型阻燃剂。它与绿色环保发展的国家概念相吻合。荧光粉含量高达18%〜20%,阻燃性能极佳。

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