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Process for the conversion of feedstock obtained from renewable sources comprising a pretreatment of said feedstock by hot dephospatation

机译:将从可再生资源中获得的原料转化的方法,包括通过热脱磷对所述原料进行预处理

摘要

Process for pretreatment of crude vegetable or animal oil comprises passing the oil in a reactor comprising at least one fixed bed of at least one adsorbent comprising a porous refractory oxide free of catalytic metals comprising groups of 6 and 8-12, at a temperature of 130-320[deg] C, a pressure of 0.1-7 MPa with a residence time of the oil on the fixed bed of 0.1-1 hour. An independent claim is included for a process for the production of a middle distillates base comprising (a) the pretreatment process; (b) hydrotreatment of the pre-treated effluent from the step (a) in the presence of at least one fixed bed catalyst, at a temperature of 200-450[deg] C, under a pressure of 1-10 MPa, an hourly space velocity of 0.1-10 h - 1and in the presence of a total amount of hydrogen mixed with filler such as the ratio of hydrogen/feed is 70-1000 Nm 3of hydrogen/m 3of filler; and (c) separating hydrogen, gas and at least one diesel base from the hydrotreated effluent from the step (b).
机译:粗植物油或动物油的预处理方法包括使油在130℃的温度下通过反应器,该反应器包括至少一个至少一种吸附剂的固定床,所述至少一种吸附剂包括不含催化金属的多孔难熔氧化物,所述催化金属包含6和8-12族。 -320℃,压力为0.1-7MPa,油在固定床上的停留时间为0.1-1小时。对于生产中间馏分油基料的方法包括独立的权利要求,所述方法包括:(a)预处理方法; (b)在至少一种固定床催化剂的存在下,在200-450℃的温度下,在1-10MPa的压力下,每小时对步骤(a)中的预处理流出物进行加氢处理。空速为0.1-10h-> 1>,并且在存在与填料混合的总量为氢的情况下,例如氢/进料的比例为70-1000 Nm 3>氢/ m 3>填料; (c)从步骤(b)的加氢处理的流出物中分离氢,气体和至少一种柴油碱。

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