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PROCESS FOR PRODUCING A SUPPORTED COBALT-BASED FISCHER- TROPSCH SYNTHESIS CATALYST BASED ON COBALT

机译:基于钴的支持的基于钴的费-托合成催化剂的制备方法

摘要

FIELD: chemistry.;SUBSTANCE: method of preparing the catalyst involves: at the first activation step, treating particles of the supported cobalt-based Fischer-Tropsch catalyst precursor, having a catalyst support saturated with cobalt and containing cobalt oxide, with a hydrogen-containing reducing gas or nitrogen-containing gas at a first heating rate HR1 until temperature of the precursor reaches a value T1 where 80°C≤T1≤180°C, to form a partially treated catalyst precursor; at the second activation step, treating the partially treated catalyst precursor with a hydrogen-containing reducing gas at a second heating rate HR2, where 0≤HR2HR1, for a period of time t1 where t1 is equal to 0.1-20 hours, to form a partially reduced precursor, and then at the third activation step, treating the partially reduced catalyst precursor with a hydrogen-containing reducing gas at a third heating rate HR3, where HR3HR2, until the partially reduced precursor reaches a temperature T2, where 300°C≤T2≤600°C and holding the partially reduced catalyst precursor at T2 for a time t2, where t2 is equal to 0-20 hours, to form an activated supported cobalt-based Fischer-Tropsch catalyst.;EFFECT: obtaining a catalyst with high activity.;13 cl, 7 tbl, 7 ex
机译:技术领域:化学物质;催化剂的制备方法包括:在第一活化步骤中,用氢饱和的催化剂处理负载的钴基费-托催化剂前体的颗粒,该催化剂前体具有被钴饱和并且含有氧化钴的催化剂载体。以第一加热速率HR1包含还原性气体或含氮气体,直到前驱物的温度达到80°C≤T 1 ≤180°C的值T 1 为止,形成部分处理的催化剂前体;在第二活化步骤中,在第二加热速率HR2(0≤HR2 1 ,其中t < Sub> 1 等于0.1-20小时,以形成部分还原的前体,然后在第三活化步骤中,在第三加热速率HR3下,用含氢的还原性气体处理部分还原的催化剂前体,其中HR3> HR2,直到部分还原的前体达到温度T 2 ,其中300°C≤T 2 ≤600°C并将部分还原的催化剂前体保持在T 2 持续时间t 2 ,其中t 2 等于0-20小时,以形成激活的受支持的钴基费-托效果:获得高活性的催化剂; 13 cl,7 tbl,7 ex

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