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METHOD FOR COMPLEX PROCESSING OF SERPENTINITE

机译:亚硒酸盐的复杂加工方法

摘要

FIELD: chemistry.;SUBSTANCE: invention can be used to produce magnesium chloride, silica and red pigment. Serpentinite calcined at 680-750°C is treated with 4-8% hydrochloric acid solution with weight ratio of serpentinite to hydrochloric acid equal to 1:(15-40). The hot pulp is then decanted and filtered. The residue is dried to obtain silica, the filtrate is evaporated and silicic acid is separated. After separating silicic acid in form of sol-gel, hydrochloric acid is added to a solution containing magnesium and iron (III) chlorides until 4-8% hydrochloric acid solution is obtained. The obtained hydrochloric acid solution is used to treat a new portion of serpentinite. Further, the decantation, filtration, evaporation of filtrate, separation of silicic acid and treatment of the obtained solution with hydrochloric acid are repeated 3-5 times using new portions of calcined serpentinite. The solution concentrated that way at 90°C is mixed with serpentinite and filtered. Magnesium chloride is separated from the residue which contains iron (III) hydroxide. Said residue is treated at 350-400°C to obtain red pigment.;EFFECT: invention simplifies the processing serpentinite, improves environmental safety and reduces expenses and wastes.;1 dwg, 1 ex
机译:领域:化学;物质:本发明可用于生产氯化镁,二氧化硅和红色颜料。用4-8%的盐酸溶液处理在680-750℃下煅烧的蛇纹石,蛇纹石与盐酸的重量比等于1:(15-40)。然后将热浆倒出并过滤。将残余物干燥以获得二氧化硅,蒸发滤液并分离硅酸。在以溶胶-凝胶形式分离硅酸之后,将盐酸添加到包含氯化镁和氯化铁(III)的溶液中,直到获得4-8%的盐酸溶液。所获得的盐酸溶液用于处理新部分的蛇纹石。此外,使用新的煅烧的蛇纹石,将倾析,过滤,滤液的蒸发,硅酸的分离以及用盐酸处理所得溶液重复3-5次。在90°C下以这种方式浓缩的溶液与蛇纹石混合并过滤。从含有氢氧化铁(III)的残留物中分离出氯化镁。所述残余物在350-400℃下处理以获得红色颜料。效果:本发明简化了蛇纹石的加工,提高了环境安全性并减少了费用和浪费。1 dwg,1 ex

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