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METHOD OF ANALYSING OPTICAL AND STRUCTURAL ISOMERS
METHOD OF ANALYSING OPTICAL AND STRUCTURAL ISOMERS
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机译:光学和结构异构体的分析方法
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FIELD: physics.;SUBSTANCE: method of analysing optical and structural isomers involves separation of the analysed mixture on a composite liquid crystal sorbent which contains a smectic-nematic liquid crystal of 4-n-octyloxy-4'-cyanobiphenyl and chiral macrocyclic modified β-cyclodextrin. The retention characteristic of the analysed substances is then determined from results of measuring chromatographic signals from obtained chromatographs. The chiral macrocyclic additive used is modified β-cyclodextrin - (heptakis-2,3,6-O-acetyl) - β-cyclodextrin in amount of 10% of the mass of the liquid crystal.;EFFECT: high enantioselectivity of analysis with retention of structural selectivity, which enables to separate optical and structural isomers in a single chromatographic analysis cycle.;1 tbl, 1 ex
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机译:领域:物理;物质:分析光学和结构异构体的方法包括在复合液晶吸附剂上分离分析混合物,该吸附剂包含4-正辛氧基-4'-氰基联苯和手性大环改性β的近晶向列型液晶-环糊精。然后根据获得的色谱仪的色谱信号测量结果确定分析物的保留特性。所使用的手性大环添加剂是修饰的β-环糊精-(庚基2,3,6-O-乙酰基)-β-环糊精,含量为液晶质量的10%;效果:高对映选择性并保留选择性,可以在一个色谱分析循环中分离旋光异构体和结构异构体。; 1 tbl,1 ex
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